“…This result suggests that the crystalline anisotropy is low between along the < 112 > and < 110 > directions lying within the (111) plane. This behavior is consistent with the low magnetocrystalline anisotropy of the LSMO layers measured by Mn XMCD, which has been observed in (111)-oriented single layer LSMO film 47 .…”
Section: X-ray Magnetic Linear Dichroism Spectroscopy and Microscopysupporting
Epitaxial La 0.7 Sr 0.3 MnO 3 (LSMO)/La 0.7 Sr 0.3 FeO 3 (LSFO) superlattices serve as model systems to explore the magnetic structure and exchange coupling at (111)-oriented perovskite oxide interfaces. The (111) orientation possesses a buckled honeycomb structure resembling that of graphene with the stacking of highly polar layers. Furthermore, the bulk LSFO magnetic structure suggests that an ideal (111) interface should have fully uncompensated antiferromagnetic (AF) moments leading to exchange bias interactions. Detailed soft x-ray magnetic spectroscopy and microscopy reveal that interfacial effects and ultrathin superlattice sublayers can stabilize orientations of the LSFO AF spin axis which differ from that of LSFO films and LSMO/LSFO bilayers. A portion of the AF moments can be reoriented to an arbitrary direction by a moderate external magnetic field through spin-flop coupling with the ferromagnetic LSMO sublayers that have low magnetocrystalline anisotropy in the (111) plane.
“…This result suggests that the crystalline anisotropy is low between along the < 112 > and < 110 > directions lying within the (111) plane. This behavior is consistent with the low magnetocrystalline anisotropy of the LSMO layers measured by Mn XMCD, which has been observed in (111)-oriented single layer LSMO film 47 .…”
Section: X-ray Magnetic Linear Dichroism Spectroscopy and Microscopysupporting
Epitaxial La 0.7 Sr 0.3 MnO 3 (LSMO)/La 0.7 Sr 0.3 FeO 3 (LSFO) superlattices serve as model systems to explore the magnetic structure and exchange coupling at (111)-oriented perovskite oxide interfaces. The (111) orientation possesses a buckled honeycomb structure resembling that of graphene with the stacking of highly polar layers. Furthermore, the bulk LSFO magnetic structure suggests that an ideal (111) interface should have fully uncompensated antiferromagnetic (AF) moments leading to exchange bias interactions. Detailed soft x-ray magnetic spectroscopy and microscopy reveal that interfacial effects and ultrathin superlattice sublayers can stabilize orientations of the LSFO AF spin axis which differ from that of LSFO films and LSMO/LSFO bilayers. A portion of the AF moments can be reoriented to an arbitrary direction by a moderate external magnetic field through spin-flop coupling with the ferromagnetic LSMO sublayers that have low magnetocrystalline anisotropy in the (111) plane.
“…2(c) were measured at 10 K after cooling with an applied field of 2 T along the in-plane [110] direction. (111)-oriented LSMO thin films have low magnetocrystalline anisotropy [16] and a low coercive field of 1 mT, which is also the case for the bilayer with a thick LSMO sublayer with a coercive field of 2 mT. In comparison, a coercivity enhancement was found in all three superlattices, which is a signature of exchange coupling, though the lack of horizontal shifts suggests that the form of exchange coupling is not exchange bias.…”
Section: A Structural Characterizationmentioning
confidence: 86%
“…Finally, the orientation of the films also plays an important role. (001)-oriented La 0.7 Sr 0.3 MnO 3 (LSMO) films under tensile strain have biaxial anisotropy along the in-plane 110 axes [15], while (111)-oriented LSMO films have low magnetocrystalline anisotropy in the (111) plane with a sixfold symmetry along the 110 and 11 2 directions [i.e., two low-index families of directions lying within the (111) plane] [16]. Among these tuning parameters, the study of the effect of orientation on the behavior of perovskite oxide thin films has been comparatively limited, with most research being focused on (001)-oriented perovskite heterostructures.…”
“…These approaches include using chemical pressure, 5 cation size effects, 6 and doping in bulk oxides. In addition, epitaxial strain, 7,8 proximity and confinement effects, [9][10][11][12][13] and substrate orientation (geometric lattice engineering) in heterostructures [14][15][16][17] and superlattices 18,19 of thin film oxides.…”
We investigate the effect of the degree of metal-oxygen octahedral facesharing on the mechanical and electronic properties of d 0 BaTiO3 and d 3 BaMnO3. We find that increased facesharing softens the elastic constants of both materials due to the increased volume per atom, with polar distortions also contributing to the reduction in the bulk modulus. Owing to orbital filling in the d manifold, we find the electronic band gap of BaTiO3 is relatively unaffected by changes in percent facesharing whereas the band gap of BaMnO3 increases by more than 200 % as the percent facesharing increases from 0 % (cubic perovskite) to 100 % (hexagonal BaNiO3 perovskite). We identify that the trigonal distortions present in the face-connected polymorphs represent useful atomistic structural knobs to tune band structure in hexagonal perovskites. Our results indicate that facesharing hexagonal polymorphs provide an expanded oxides arena with additional structural flexibility beyond the usual fully-corner-connected perovskites for property control.
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