Amorphous alloy refers to the orderly arrangement of the internal structure of various substances in nature. Amorphous solid materials include amorphous inorganic materials, amorphous polymers, and amorphous alloys. Amorphous alloys, also known as glassy alloys or metallic glasses, are atomically condensed, long-range disordered, and short-range ordered alloy materials that have the distinctive properties of both metals and glasses. Ligament injury is damage caused by different degrees of damage to the ligaments of a certain part of the body. The purpose of this paper is to investigate amorphous alloys and ferroelectric nanomaterials and the repair of athletic ligament injuries in the soccer game, using the excellent properties of amorphous alloys and ferroelectric nanomaterials to solve the problem of athletic injuries. Knee and ankle injuries and muscle strains account for a large percentage of soccer injuries. In this paper, researches and explorations have been conducted on the preparation of new composite magnetic nanomaterials, the construction of immunosensor interfaces, and the development of new signal amplification and renewable immunosensors. The rehabilitation effect of the medial collateral ligament of the athlete’s knee joint is used as the research object, and various methods are used. In-depth investigation and research and statistical analysis of the data obtained one by one were carried out. The experimental results in this article show that from the age of ligament injury, the number of people between 18 and 20 is relatively small, and the number of people aged 20–40 is relatively large. The number of people who have been trained for three years and above is 5, and the proportion of ligament injuries is 0.8%; the number of training for two years is 33, and the proportion of ligament injuries is 13.7%, the number of training for one year is 98, and the proportion of ligament injuries is 40.7%, and the number of training for six months is 105, and the proportion of ligaments is 44.8%.