Functionality of polymeric coating, especially in terms of anti-corrosive properties and stability, can be negatively influenced by formation of either bacterial and/or fungal biofilm on its surface. Inhibition of biofilm formation together with improved anti-corrosive properties can be achieved by modification of pigments. Herein, the commercial epoxy-ester resin based polymeric coating was filled with various pigments (natural silicon dioxide diatomite, natural wollastonite, tungstate and molybdate). Pigments was modified by conducting polymers (polyaniline phosphate, polypyrrole phosphate, poly(pphenylenediamine) phosphate and ZnFe2O4). Impact of modified pigments on the surface energy and formation of bacterial and fungal biofilm were tested. The use of various biofilm forming species of both the bacteria and fungi leads to the filling of knowledge gap about their behavior on polymeric coatings.