Cu(I/II)-Co(II/III) photocatalyst with intrinsic electron transport centre for photoreduction of chromium(VI) and photodegradation of methyl violet

Saikia, Sayanika; Saikia, Lakshi; Lee, Seonghwan; Park, Young-Bin; Saha, Rafikul Ali; Khanam, Salma A.; Zaki, Magdi E.A.; Bania, Kusum K.

doi:10.1016/j.jece.2024.112344

Journal of Environmental Chemical Engineering

2024

DOI: 10.1016/j.jece.2024.112344

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Cu(I/II)-Co(II/III) photocatalyst with intrinsic electron transport centre for photoreduction of chromium(VI) and photodegradation of methyl violet

Sayanika Saikia,

Lakshi Saikia,

Seonghwan Lee

et al.

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Copper Sulfide based Photocatalysts, Electrocatalysts and Photoelectrocatalysts: Innovations in Structural Modulation and Application

Li,

Wang

2024

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Copper sulfides (CuxS, 1 ≤ x ≤ 2) are notable for their unique photoelectric properties and potential applications, particularly in photo/electrocatalysis. These materials are valued for their tunable band gap, near‐infrared optical characteristics, and plasmonic resonance effects. However, challenges such as low catalytic activity and limited stability impede their practical applications. This review addresses these issues by exploring advanced strategies for electronic structure modulation, including atomic doping, shape alteration, heterojunction construction, and defect introduction to enhance catalytic efficiency. A detailed analysis of the optical and electrical properties of CuxS across various stoichiometric ratios and crystal structures is provided, offering a comprehensive overview of their applications in photocatalysis, electrocatalysis, and photo/electrocatalysis. Additionally, the review synthesizes current knowledge and highlights the potential of these strategies to optimize CuxS‐based photo/electrocatalysts, proposing future research directions to bridge the gap between theoretical studies and practical applications. This work underscores the importance of CuxS in photo/electrocatalysis and aims to inspire further innovation and exploration in this field, emphasizing its significance in material science and engineering.

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Copper Sulfide based Photocatalysts, Electrocatalysts and Photoelectrocatalysts: Innovations in Structural Modulation and Application

Li,

Wang

2024

Small

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Xie,

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Deng

et al. 2024

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Photodegradation of berberine hydrochloride at the interface of 1D–2D nanohybrid of nickel ferrite supported on reduced graphene oxide

Saikia,

Khanam,

Kandali

et al. 2025

RSC Sustain.

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Cu(I/II)-Co(II/III) photocatalyst with intrinsic electron transport centre for photoreduction of chromium(VI) and photodegradation of methyl violet

Cited by 3 publications

References 73 publications

Copper Sulfide based Photocatalysts, Electrocatalysts and Photoelectrocatalysts: Innovations in Structural Modulation and Application

Copper Sulfide based Photocatalysts, Electrocatalysts and Photoelectrocatalysts: Innovations in Structural Modulation and Application

Enhanced photocatalytic aerobic oxidative desulfurization of diesel over FeMo6Ox nanoclusters decorated on CuS nanosheets

Photodegradation of berberine hydrochloride at the interface of 1D–2D nanohybrid of nickel ferrite supported on reduced graphene oxide

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