Cu2+-phthalocyanine and Co2+-perfluorophthalocyanine incorporated inside Y faujasite and mesoporous MCM-41 as heterogeneous catalysts for the oxidation of cyclohexane

Sulphonated cobalt phthalocyanine–MCM-41: An active photocatalyst for degradation of 2,4-dichlorophenol

“…Therefore, functionalization of surface is necessary to convert MCM-41 materials to those holding desirable properties [44]. Even though there have been reports on the use of metallophthalocyanines anchored onto the surface of MCM-41 and using them as catalyst in the oxidation of aromatic compounds [45][46][47][48][49][50], their employment as photocatalysts have not received much attention [51].…”

Zinc(II) phthalocyanines immobilized in mesoporous silica Al-MCM-41 and their applications in photocatalytic degradation of pesticides

“…The confinement of metal complexes within the constrained environment of ordered mesoporous oxides is particularly important, and has been actively developed since the discovery of M41S family [16][17][18]20,[22][23][24][25][26][27][28][29]. Although there are reports on the use of metallophthalocyanines anchored onto the surface of Al-MCM-41 as catalysts in the oxidation of aromatic compounds [17,[23][24][25][26][27][28][29], their employment as photocatalysts has not received much attention [16,18,20,21].…”

“…Although there are reports on the use of metallophthalocyanines anchored onto the surface of Al-MCM-41 as catalysts in the oxidation of aromatic compounds [17,[23][24][25][26][27][28][29], their employment as photocatalysts has not received much attention [16,18,20,21].…”

Phytol‐modified heme in mesoporous silica: Conjugates as models of hemoproteins

“…They are potential hosts for the inclusion of bulky organometallic and inorganic complexes, and offer nanoscale spaces for the synthesis of robust metal clusters such as Pt nano-wires . Furthermore, mesoporous ordered channels (2-10 nm in diameter) can uniformly occlude not only some larger metal complexes such as porphyrin (Murata et al, 2001;Tachibana et al, 1998;Xu et al, 2001;Zhou and Honma, 1998) and phtalocyanine (Armengol et al, 1999), but also enzymes such as peroxidase (Takahashi et al, 2000) and trypsin (Yiu et al, 2001), yielding supramolecular hybrid composites. Host-guest reactions such as interaction or inclusion phenomena are expected to be useful in arranging the metal-complex molecules.…”