Cubic zirconia in &gt;2370 °C impact melt records Earth's hottest crust

Shatter cones are diagnostic for the recognition of meteorite impact craters. They are unambiguously identifiable in the field and the only macroscopic shock deformation feature. However, the physical boundary conditions and exact formation mechanism(s) are still a subject of debate. Melt films found on shatter cone surfaces may allow the constraint of pressure–temperature conditions during or immediately after their formation. Within the framework of the MEMIN research group, we recovered 24 shatter cone fragments from the ejecta of hypervelocity impact experiments. Here, we focus on silicate melt films (now quenched to glass) found on shatter cone surfaces formed in experiments with 20–80 cm sized sandstone targets, impacted by aluminum and iron meteorite projectiles of 5 and 12 mm diameter at velocities of 7.0 and 4.6 km s−1, respectively. The recovered shatter cone fragments vary in size from 1.2 to 9.3 mm. They show slightly curved, striated surfaces, and conical geometries with apical angles of 36°–52°. The fragments were recovered from experiments with peak pressures ranging from 46 to 86 GPa, and emanated from a zone within 0.38 crater radii. Based on iSale modeling and petrographic investigations, the shatter coned material experienced low bulk shock pressures of 0.5–5 GPa, whereas deformation shows a steep increase toward the shatter cone surface leading to localized melting of the rock, resulting in both vesicular as well as polished melt textures visible under the SEM. Subjacent to the melt films are zones of fragmentation and brittle shear, indicating movement away from the shatter cone apex of the rock that surrounds the cone. Smearing and extension of the melt film indicates subsequent movement in opposite direction to the comminuted and brecciated shear zone. We believe the documented shear textures and the adjacent smooth melt films can be related to frictional melting, whereas the overlying highly vesiculated melt layer could indicate rapid pressure release. From the observation of melting and mixing of quartz, phyllosilicates, and rutile in this overlying texture, we infer high, but very localized postshock temperatures exceeding 2000 °C. The melted upper part of the shatter cone surface cross‐cuts the fragmented lower section, and is accompanied by PDFs developed in quartz parallel to the {11true2false¯2} plane. Based on the overprinting textures and documented shock effects, we hypothesize shatter cones start to form during shock loading and remain an active fracture surface until pressure release during unloading and infer that shatter cone surfaces are mixed mode I/II fracture surfaces.

Section: Discussionsupporting

confidence: 87%

Section: Discussionmentioning

confidence: 98%

Section: Melt Composition and P-t Constraintsmentioning

confidence: 88%

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Petrographic investigation of shatter cone melt films recovered from MEMIN impact experiments in sandstone and iSALE modeling of their formation boundary conditions

Wilk

Hamann

Fazio

et al. 2018

“…), particularly considering that these tektites had nondigested crystals likely suggesting a lower peak temperature compared to their crystal‐free counterparts, (2) the presence of cubic zirconia in the Mistastin impact melt rock (>2400 °C; Timms et al. ), (3) the temperature derived from hydrocode‐based numerical simulations of the Moldavite genesis (~3100 °C; Stöffler et al. ) and hydrocode models of Collins et al.…”

Section: Discussionmentioning

confidence: 99%

Ultraprecise age and formation temperature of the Australasian tektites constrained by⁴⁰Ar/³⁹Ar analyses

Jourdan

Nomade

Wingate

et al. 2019

The Australasian tektites are quench melt glass ejecta particles distributed over the Asian, Australian, and Antarctic regions, the source crater of which is currently elusive. New 40Ar/39Ar age data from four tektites: one each from Thailand, China, Vietnam, and Australia measured using three different instruments from two different laboratories and combined with published 40Ar/39Ar data yield a weighted mean age of 788.1 ± 2.8 ka (±3.0 ka, including all sources of uncertainties) (P = 0.54). This age is five times more precise compared to previous results thanks, in part, to the multicollection capabilities of the ARGUS VI noble gas mass spectrometer, which allows an improvement of almost fourfold on a single plateau age measurement. Diffusion experiments on tektites combined with synthetic age spectra and Monte Carlo diffusion models suggest that the minimum temperature of formation of the Thai tektite is between 2350 °C and 3950 °C, hence a strict minimum value of 2350 °C.

“…; Timms et al. ). It can occur after entrainment of shocked zircon into impact melt or as a result of decompression after passage of the shock wave.…”

Section: Discussionmentioning

confidence: 99%

Linking shock textures revealed by BSE, CL, and EBSD with U‐Pb data (LA‐ICP‐MS and SIMS) from zircon from the Araguainha impact structure, Brazil

Hauser

Reimold

Cavosie

et al. 2019

Self Cite

A silicious impact melt rock from polymict impact breccia of the northern part of the alkali granite core of the Araguainha impact structure, central Brazil, has been investigated. The melt rock is thought to represent a large mass of impact‐generated melt in suevite. In particular, a diverse population of zircon grains, with different impact‐induced microstructures, has been analyzed for U‐Pb isotopic systematics. Backscattered electron and cathodoluminescence images reveal heterogeneous intragrain domains with vesicular, granular, vesicular plus granular, and vesicular plus (presumably) baddeleyite textures, among others. The small likely baddeleyite inclusions are not only preferentially located along grain margins but also occur locally within grain interiors. LA‐ICP‐MS U‐Pb data from different domains yield lower intercept ages of 220, 240, and 260 Ma, a result difficult to reconcile with the previous “best age” estimate for the impact event at 254.7 ± 2.7 Ma. SIMS U‐Pb data, too, show a relatively large range of ages from 245 to 262 Ma. A subset of granular grains that yielded concordant SIMS ages were analyzed for crystallographic orientation by EBSD. Orientation mapping shows that this population consists of approximately micrometer‐sized neoblasts that preserve systematic orientation evidence for the former presence of the high‐pressure polymorph reidite. In one partially granular grain (#36), the neoblasts occur in linear arrays that likely represent former reidite lamellae. Such grains are referred to as FRIGN zircon. The best estimate for the age of the Araguainha impact event from our data set from a previously not analyzed type of impact melt rock is based on concordant SIMS data from FRIGN zircon grains. This age is 251.5 ± 2.9 Ma (2σ, MSWD = 0.45, p = 0.50, n = 4 analyses on three grains), indistinguishable from previous estimates based on zircon and monazite from other impact melt lithologies at Araguainha. Our work provides a new example of how FRIGN zircon can be combined with in situ U‐Pb geochronology to extract an accurate age for an impact event.