Current Efficiency Studies of the Hooker Type S Chlorine Cell

Murray, Royce; Kircher, M. S.

doi:10.1149/1.3071606

Cited by 10 publications

(21 citation statements)

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“…A typical chromatogram of chlorine cell gas is illustrated in Figure 3. Good resolution of all components is obtained in less than 20 minutes, whereas the same analysis by wet chemical methods (2) requires much longer. When compared to values obtained by wet chemical methods, the analyses in volume % 1382 • The chromatogram is read by measuring the peaks and applying predetermined correction factors to the measurements.…”

Section: Discussionmentioning

confidence: 99%

Analysis of Chlorine Cell Gas by Gas Chromatography

Neely¹

1960

Anal. Chem.

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Section: Discussionmentioning

confidence: 99%

Analysis of Chlorine Cell Gas by Gas Chromatography

Neely¹

1960

Anal. Chem.

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“…Some of the chlorine gas produced at the anode will take part in chemical side reactions resulting in unwanted impurities. (4,5). A reaction too slow to reach equilibrium is the chemical chlorate formation 2HOC1 + OCI--> C103-+ 2H + + 2(21- [7] the rate equation of which is also known.…”

Section: The Mechanistic Base Of the Modelmentioning

confidence: 99%

“…The chlorine will dissolve in the anolyte and will react to form trichloride ion and hydrolysis products C12 (g) ~ C12 (aq) [3] C12(aq) + C1-~-C13- [4] C12 (aq) + H20 ~ HOC1 + H + + C1- [5] HOCI~ H + + OC1- [6] These reactions are considered to be in equilibrium in the anolyte; all equilibrium constants are known. This is the parametric equation fitted to experimental data.…”

Section: The Mechanistic Base Of the Modelmentioning

confidence: 99%

“…OC1-+ H2-~ CI--k H20 [12] The reduction of hypochlorite in the chlorine ceil catholyte has been well documented (4)(5)(6)(7)(8), and it is an experimental fact that the catholyte overflow of a normally operating cell does not contain any hypochlorite. There is no basis for dividing the reduction between the electrochemical and the chemical routes, but, as long as the reduction is complete, it is immaterial for the present purposes.…”

Section: The Mechanistic Base Of the Modelmentioning

confidence: 99%

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A Mechanistic Model for the Calculation of Material Balance for a Diaphragm‐Type Chlorine Caustic Cell

Nagy¹

1977

J. Electrochem. Soc.

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Publication costs o] this article were assisted bythe IB2/f Corporation. * E l e c t r o c h e m i c a l Society Active Member. i P r e s e n t a d d r e s s : A r g o n n e N a t i o n a l L a b o r a t o r y , C h e m i c a l Engineering Division, Argonne, Illinois 60439. K e y w o r d s : chlorine, caustic, electrolysis, diaphragm, computer.) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 35.8.191.249 Downloaded on 2015-03-31 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 35.8.191.249 Downloaded on 2015-03-31 to IP Vol. 124, No. i A DIAPHRAGM-TYPE CHLORINE CAUSTIC CELL ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 35.8.191.249 Downloaded on 2015-03-31 to IP

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“…On the other hand, although the diaphragm-type chlorine cell accounts for a major share of the chlorine produced in the United States, comparatively few papers have been published on the diaphragm cell (1)(2)(3)(4).…”

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confidence: 99%