Cycl[2,2,4]azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring

Ruan, Lan; Luo, Wanhua; Zhang, Haifan; Liu, Peng; Shi, Yong; An, Peng

doi:10.1039/d3sc05515a

Chem. Sci.

2024

DOI: 10.1039/d3sc05515a

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Cycl[2,2,4]azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring

Lan Ruan,

Wanhua Luo,

Haifan Zhang

et al.

Abstract: The development of non-alternant nanographenes has attracted considerable attention due to their unique photophysical properties. Herein, we reported a novel aza-doped, non-alternant nanographene (NG) 1 by embedding the cycl[2,2,4]azine unit...

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Cited by 4 publications

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Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Luo,

Liu

2024

Angewandte Chemie

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Introduction of nonhexagons and/or heteroatoms allows for finely tuning the physicochemical properties of nanographenes. Heteroatoms doping have dominated the modulation of nanographenes with tunable bandgap, rich electrochemical activities and so on. The pair of nonhexagons, for instance, pentagon‐heptagon pairs, have furnished nanographenes with aromatic and/or antiaromatic characteristics, open‐shell properties and so on. In order to meet the growing demand for versatile nanographenes in materials science, research on novel nanographenes with heteroatom doped nonhexagonal pairs has been aroused in recent years. In this review, we focus on nanographenes with nitrogen‐doped nonhexagonal paris including the synthesis, structure analysis, photophysical properties, and potential applications in organic devices.

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Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Luo,

Liu

2024

Angewandte Chemie

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Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Luo,

Liu

2024

Angew Chem Int Ed

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Heptacyclic aromatic hydrocarbon isomers with two azulene units fused

Guo,

Du,

et al. 2024

Chem. Sci.

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Cycl[2,2,4]azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring

Abstract: The development of non-alternant nanographenes has attracted considerable attention due to their unique photophysical properties. Herein, we reported a novel aza-doped, non-alternant nanographene (NG) 1 by embedding the cycl[2,2,4]azine unit...

Cited by 4 publications

References 94 publications

Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Non‐Alternant Nanographenes Bearing N‐Doped Non‐Hexagonal Pairs: Synthesis, Structural Analysis and Photophysical Properties

Heptacyclic aromatic hydrocarbon isomers with two azulene units fused

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