Darstellung und Polymerisation von S-Vinyl-methylendisulfonen

Diefenbach, H.; Müller, F. H.; Ringsdorf, Helmut

doi:10.1007/bf01500632

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Electron Deficient S-vinyl Groups1

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1966

2022

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Cited by 6 publications

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“…149 Indeed, already in 1961 Overberger and Schiller 150 obtained only dimers when attempting to generate polyvinyl sulfone with potassium, which they attributed to side reactions due to the acidic CH 2 group. The substituent was again found to have a crucial influence on the polymerization behavior, as Diefenbach et al 151 showed a few years later. He tested polymerizations of disulfone derivatives comprising SO 2 -CH 2 -SO 2 adjacent to a vinyl group using potassium tert -butylate as initiator.…”

Section: Electron Deficient S-vinyl Groupsmentioning

confidence: 88%