Das Trifluor‐nitroso‐methan, CF
            <sub>3</sub>
            .NO (III.)

Ruff, Otto; Giese, M.

doi:10.1002/cber.19360690411

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Introduction2

The Action Of Elementary Fluorine Upon Organic Compounds1

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1947

2013

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Cited by 11 publications

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“…In a final article of this series, Ruff and Giese (80) carried out an exhaustive study of the third portion, described above as a blue compound (m.p. about -150°C., b.p.…”

Section: The Action Of Elementary Fluorine Upon Organic Compoundsmentioning

confidence: 99%

The Action of Elementary Fluorine upon Organic Compounds.

Bigelow¹

1947

Chem. Rev.

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“…In a final article of this series, Ruff and Giese (80) carried out an exhaustive study of the third portion, described above as a blue compound (m.p. about -150°C., b.p.…”

Section: The Action Of Elementary Fluorine Upon Organic Compoundsmentioning

confidence: 99%

The Action of Elementary Fluorine upon Organic Compounds.

Bigelow¹

1947

Chem. Rev.

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“…Attempts to prepare difluoroaminocarbonyl fluoride, F 2 NC(O)F, were first reported by Ruff and Giese in 1936. 1 When trifluoronitrosomethane, CF 3 NO, contacts aqueous sodium hydroxide, nearly quantitative conversion to its isomer [F 2 NC(O)F] occurs. 2 However, some controversies appeared when Haszeldine and Jander concluded that the earlier reported compound was either perfluoroethane (C 2 F 6 ) or perfluoromethylamine (CF 3 NF 2 ) and, therefore, that F 2 NC(O)F was elusive so far.…”

Section: Introductionmentioning

confidence: 99%

“…Attempts to prepare difluoroaminocarbonyl fluoride, F 2 NC(O)F, were first reported by Ruff and Giese in 1936 . When trifluoronitrosomethane, CF 3 NO, contacts aqueous sodium hydroxide, nearly quantitative conversion to its isomer [F 2 NC(O)F] occurs .…”

Section: Introductionmentioning

confidence: 99%

Conformational and Structural Determination of F₂NC(O)F and F₂NC(O)NCO. A Joint Experimental and Theoretical Study

et al. 2009

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The vibrational properties of two difluoroaminocarbonyl species were analyzed by recording the FTIR spectra of the vapor for difluoroaminocarbonyl fluoride, F(2)NC(O)F, and difluoroaminocarbonyl isocyanate, F(2)NC(O)NCO. Moreover, the Raman spectrum of liquid F(2)NC(O)NCO was obtained. Vibrational assignments were made on the basis of a normal coordinate analysis and the evaluation of the band contours appearing in the FTIR spectrum of the vapor. The conformational space of both difluoroaminocarbonyl derivatives were studied by using the B3LYP and MP2 level of theory with extended basis sets [6-311+G(3df) and aug-cc-pVTZ]. Only one conformation belonging to the C(1) symmetry point group is expected for F(2)NC(O)F, whereas the overall evaluation of experimental and theoretical results suggests the existence of a mixture of two conformers for F(2)NC(O)NCO at room temperature. Its relative abundance of the most stable syn form (C=O double bond syn with respect to the N=C=O group) was estimated to be 56(5) %.

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