KEY POINTS 14We present a method to calculate continuously saturations of pore phases during hydrate 15 formation/dissociation from pressure and temperature. 16In our experiment up to 26% hydrate co-existed with about 12% gas in three hydrate formation 17 cycles with 10 and 55 MPa differential pressure 18We suggest the dominant mechanism for gas and hydrate co-existence in our experiment is 19 formation of hydrate-enveloped gas bubbles. 20
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ABSTRACT 22Methane hydrate saturation estimates from remote geophysical data and borehole logs are needed 23 to assess the role of hydrates in climate change, continental slope stability, and energy resource 24 potential. Here, we present laboratory hydrate formation/dissociation experiments in which we 25 determined the methane hydrate content independently from pore pressure and temperature, and 26 from electrical resistivity. Using these laboratory experiments, we demonstrate that hydrate 27 formation does not take up all the methane gas or water even if the system is under two phase 28 water-hydrate stability conditions and gas is well distributed in the sample. The experiment 29 started with methane gas and water saturations of 16.5% and 83.5% respectively; during the 30 experiment, hydrate saturation proceeded up to 26% along with 12% gas and 62% water 31 remaining in the system. The co-existence of hydrate and gas is one possible explanation for 32 discrepancies between estimates of hydrate saturation from electrical and acoustic methods. We 33 suggest that an important mechanism for this co-existence is the formation of a hydrate film 34 enveloping methane gas bubbles, trapping the remaining gas inside. 35 36 3