2012
DOI: 10.1021/om2006112
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Decamethylferrocene Redox Chemistry and Gold Nanowire Electrodeposition at Salt Crystal|Electrode|Nonpolar Organic Solvent Contacts

Abstract: This report describes exploratory experimental findings for electrochemical processes in nonpolar solvents (hexane, toluene, and dichloroethane). Conventional 3 mm diameter glassy-carbon-disk electrodes are used in contact with a crystalline salt electrolyte (ammonium nitrate) immersed in nonpolar solvents. The insoluble salt is employed as a "surface thin film electrolyte", with humidity causing electrical connection from the working electrode to the SCE counterreference electrode. The organic solvents are em… Show more

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