Rota–Baxter operators
R
of weight 1 on
are in bijective correspondence to post-Lie algebra structures on pairs
, where
is complete. We use such Rota–Baxter operators to study the existence and classification of post-Lie algebra structures on pairs of Lie algebras
, where
is semisimple. We show that for semisimple
and
, with
or
simple, the existence of a post-Lie algebra structure on such a pair
implies that
and
are isomorphic, and hence both simple. If
is semisimple, but
is not, it becomes much harder to classify post-Lie algebra structures on
, or even to determine the Lie algebras
which can arise. Here only the case
was studied. In this paper, we determine all Lie algebras
such that there exists a post-Lie algebra structure on
with
.