• incidence in a SIMS instrument. The oxide layers were annealed at 950• C for 3, 6 or 8.5 min under Ar flow in a rapid thermal annealer. Temperature-dependent current-voltage (I -V -T) measurements were used in order to establish both the dielectric quality and the current transport mechanisms across the dielectric layers. Annealing for 8.5 min doubled the breakdown voltage while decreasing the leakage current by a factor of ∼18. The ohmic quality of the layers for the low field strengths decreased with the increasing annealing time, which is related to the removal of implantation damage as observed by high-resolution RBS measurements. For the high field strengths, the tunnelling effect was most dominant for the oxide annealed for 8.
INTRODUCTIONThe ion beam oxidation of Si using low-energy oxygen ions constitutes an area of both technological and basic scientific interest. Ion beam synthesis of SiO 2 layers has been employed successfully for the fabrication of semiconductoron-insulator (SOI) structures. Ultra-large-scale integration poses stringent demands on the production of SIMOX (separation by implanted oxygen structures) layers with high-quality thin Si overlayers that can be used for further epitaxial growth. One way to achieve this is through the implantation of low-energy (¾20 keV) oxygen ions followed by high-temperature annealing.1,2 It is, however, well known that the use of ion implantation in the formation of SIMOX SOI creates damage in the Si lattice, which is stable even after annealing. 3,4 Low-energy oxygen ions (¾0.1-20 keV) also are employed in SIMS to determine the depth distribution of impurities in semiconductors. The formation of a stoichiometric surface oxide layer may cause the redistribution of the impurity species being profiled, and hence degrade the depth resolution. We have studied recently the segregation Ł Correspondence to: P. N. K. Deenapanray, Department of Electronic Materials Engineering, Research School of Physical Sciences and Engineering, The Australian National University, Canberra ACT 0200, Australia. E-mail: pnk109@rsphysse.anu.edu.au Contract/grant sponsor: Professor C. Jagadish. behaviour of several ion-implanted impurities in both n-and p-type Si wafers of different resistivities.5 -7 The anomalous redistribution of impurities during the formation of an SiO 2 layer can, amongst others, be explained by the thermodynamically driven and electric-field-driven segregation effects.
-7The formation of a shallow buried SiO 2 layer during low-energy oxygen ion implantation involves several, often competing, processes such as the simultaneous implantation of oxygen ions below the Si surface and the sputter removal of the top surface layer, determined primarily by the ion energy and angle of incidence. 8 -10 In brief, the implanted oxygen ions build up to a threshold level when a buried SiO 2 layer is formed. Oxygen in excess of this threshold level rapidly diffuses out of the SiO 2 layer to react with free Si at the Si/SiO 2 interfaces. Simultaneous sputtering of the Si sur...