Structural distortions of Ar þ -irradiated SrTiO 3 , which shows room-temperature blue luminescence, were studied through synchrotron X-ray diffraction. The reciprocal-lattice maps around (114)SrTiO 3 reveal that the Ar þ -irradiated SrTiO 3 surface has expanded lattice parameters along the [001] direction due to oxygen vacancies. From an analysis of the asymmetric diffraction profile around (002)SrTiO 3 , the surface region modified by the Ar þ -irradiation is estimated to be 21 nm in depth.