Abstract:Low temperature annealing of 4H-SiC Schottky diode edge terminations formed by 30 keV Ar + implantation J. Appl. Phys. 87, 3973 (2000) The degradation mechanism of Ta Schottky contact on 4H-SiC exposed to an inductively coupled plasma ͑ICP͒ was studied using deep-level transient spectroscopy and angle-resolved x-ray photoelectron spectroscopy ͑XPS͒. Four kinds of traps T1, T2, T3, and T4 were observed in the ICP-etched sample. The T4 trap was deep in the bulk, but the shallower levels, T1, T2 and T3, were loca… Show more
“…Inductively coupled-plasma (ICP) etching can offer significant advantages with respect to RIE in terms of surface damage, due to lower ion energies and the higher plasma densities. However, even ICP causes degradation of the contact properties, as recently reported for Ta/4H-SiC diodes [15], due to the generation of deep levels in the material gap. A significant improvement of the electrical characteristic of Ni contacts was achieved in our group by annealing the devices at 600°C [14], as shown in Fig.…”
In this paper, some basic aspects related to defects and SiC devices performances are discussed. Our recent work is reviewed and inserted in the international research scenario. In particular, some issues relative to rectifying metal/SiC contacts will be treated in more detail. In fact, establishing a correlation between material defects, processing induced defects and irradiation induced defects with the electrical behaviour of Schottky contacts is extremely important for the future optimization of almost all electronic devices, sensors and particle detectors.
“…Inductively coupled-plasma (ICP) etching can offer significant advantages with respect to RIE in terms of surface damage, due to lower ion energies and the higher plasma densities. However, even ICP causes degradation of the contact properties, as recently reported for Ta/4H-SiC diodes [15], due to the generation of deep levels in the material gap. A significant improvement of the electrical characteristic of Ni contacts was achieved in our group by annealing the devices at 600°C [14], as shown in Fig.…”
In this paper, some basic aspects related to defects and SiC devices performances are discussed. Our recent work is reviewed and inserted in the international research scenario. In particular, some issues relative to rectifying metal/SiC contacts will be treated in more detail. In fact, establishing a correlation between material defects, processing induced defects and irradiation induced defects with the electrical behaviour of Schottky contacts is extremely important for the future optimization of almost all electronic devices, sensors and particle detectors.
Silicon carbide (4H-SiC) Schottky diodes have reached a mature level of technology and are today essential elements in many applications of power electronics. In this context, the study of Schottky barriers on 4H-SiC is of primary importance, since a deeper understanding of the metal/4H-SiC interface is the prerequisite to improving the electrical properties of these devices. To this aim, over the last three decades, many efforts have been devoted to developing the technology for 4H-SiC-based Schottky diodes. In this review paper, after a brief introduction to the fundamental properties and electrical characterization of metal/4H-SiC Schottky barriers, an overview of the best-established materials and processing for the fabrication of Schottky contacts to 4H-SiC is given. Afterwards, besides the consolidated approaches, a variety of nonconventional methods proposed in literature to control the Schottky barrier properties for specific applications is presented. Besides the possibility of gaining insight into the physical characteristics of the Schottky contact, this subject is of particular interest for the device makers, in order to develop a new class of Schottky diodes with superior characteristics.
“…Therefore, it is very important to understand the nature of such non-ideal behaviour, investigating to which extent the material quality and/or the surface preparation play a role in the carrier transport through the interfaces. Table 2 reports the values of the SBH ( B ) for different metal/SiC contacts, for the most common polytypes, 3C-SiC [16][17][18], 6H-SiC [19][20][21][22][23][24][25][26] and 4H-SiC [27][28][29][30][31][32][33][34][35][36]. These values are a selection among a large amount of published data.…”
Section: Nanoscale Inhomogeneity Of Schottky Barriers To N-type Sicmentioning
Abstract. Wide band gap semiconductors promise devices with performances not achievable using silicon technology. Among them, Silicon Carbide (SiC) is considered the top-notch material for a new generation of power electronic devices, ensuring the improved energy efficiency requested in the modern society. In spite of the significant progresses achieved in the last decade in the material quality, there are still several scientific open issues related to the basic transport properties at SiC interfaces and ion-doped regions that can affect the devices performances, keeping them still far from their theoretical limits. Hence, significant efforts in fundamental research at nanoscale have become mandatory to better understand the carrier transport phenomena, both at surfaces and interfaces. In this paper, the most recent experiences on nanoscale transport properties will be addressed, reviewing the relevant key points for the basic devices building blocks. The selected topics include the major concerns related to the electronic transport in metal/SiC interfaces, to the carrier concentration and mobility in ion-doped regions, and to channel mobility in metal/oxide/SiC systems. Some aspects related to interfaces between different SiC polytypes are also presented. All these issues will be discussed considering the current status and the drawbacks of SiC devices.
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