A computable structure A has degree of categoricity d if d is exactly the degree of difficulty of computing isomorphisms between isomorphic computable copies of A. Fokina, Kalimullin, and Miller showed that every degree d.c.e. in and above 0 (n) , for any n < ω, and also the degree 0 (ω) , are degrees of categoricity. Later, Csima, Franklin, and Shore showed that every degree 0 (α) for any computable ordinal α, and every degree d.c.e. in and above 0 (α) for any successor ordinal α, is a degree of categoricity. We show that every degree c.e. in and above 0 (α) , for α a limit ordinal, is a degree of categoricity. We also show that every degree c.e. in and above 0 (ω) is the degree of categoricity of a prime model, making progress towards a question of Bazhenov and Marchuk.