Dehydration of 2-Methylbutanal and Methyl Isopropyl Ketone to Isoprene Using Boron and Aluminium Phosphate Catalysts

Conversion of 2,3‐Butanediol over Phosphate Catalysts

“…The literature data contains a lot of information on different amorphous and crystalline phosphate materials and the methods of their preparation . Crystalline phosphates with α, γ, ζ structures are usually not thermally stable and convert into other crystalline forms during calcination over 300 °C.…”

Characterization of local environments in crystalline borophosphates using single and double resonance NMR

“…Besides being of interest from the point of view of fundamental science, borophosphates have also attracted attention for a variety of technological applications in catalysis and ceramic engineering [11,12], as well as for fast ion-conducting materials [19][20][21]. While the structures of the crystalline borophosphates can be analyzed using single-crystal X-ray diffraction, the most valuable information regarding the structures of amorphous systems today comes from solid-state NMR investigations.…”

“…The interest in crystalline [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15] and glassy or disordered [16][17][18][19][20][21][22][23][24][25][26][27][28] borophosphate compounds of the general composition xM 2 O-yB 2 O 3 -zP 2 O 5 (mH 2 O) has increased dramatically in recent years due to the large structural diversity that can be found in these systems. Besides being of interest from the point of view of fundamental science, borophosphates have also attracted attention for a variety of technological applications in catalysis and ceramic engineering [11,12], as well as for fast ion-conducting materials [19][20][21].…”

Influence of phosphate precursors on the structures of sodium aluminophosphate sols, gels and glasses

“…Furthermore, the preparation of thin film is possible. The preparation of amorphous aluminophosphate powders and bulk glasses has attracted considerable attention in this regard [4][5][6][7][8], because these materials are useful in a number of applications as laser devices, catalysts and catalyst supports, solid-state batteries, and hermetic seals to materials with high thermal expansion coefficients [9][10][11][12][13][14]. Since commonly used aluminum alkoxide precursors are highly reactive towards water, resulting in rapid hydrolysis and precipitation [15], the homogeneous introduction of alumina into glassy networks via the sol-gel route has been a great challenge [4][5][6][7][8].…”