Dehydration of n-Butanol on Zeolite H-ZSM-5 and Amorphous Aluminosilicate: Detailed Mechanistic Study and the Effect of Pore Confinement

Макарова, М. А.; Паукштис, E. A.; Thomas, J. M.; Williams, C.; Zamaraev, K. I.

doi:10.1006/jcat.1994.1270

Cited by 84 publications

(72 citation statements)

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“…The catalytic dehydration of butanol has been extensively studied over Brønsted acid sites of several solid acid catalysts, such as zeolites [9][10][11][12][13][14][15][16][17][18][19], amorphous alumino-silicates [12,17] and polyoxometalate (POM) clusters [20][21][22][23][24]. The dehydration reaction is accompanied by side reactions such as oligomerization, cracking and aromatization [18].…”

Section: Introductionsupporting

confidence: 42%

Reaction path analysis for 1-butanol dehydration in H-ZSM-5 zeolite: Ab initio and microkinetic modeling

John

Alexopoulos

Reyniers

et al. 2015

Journal of Catalysis

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Section: Introductionsupporting

confidence: 42%

Reaction path analysis for 1-butanol dehydration in H-ZSM-5 zeolite: Ab initio and microkinetic modeling

John

Alexopoulos

Reyniers

et al. 2015

Journal of Catalysis

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“…It consists in a temporary increase of the reaction rate when the reactant feed is switched off and replaced by an inert gas stream with the total¯ow rate kept constant. This phenomenon was also observed by Makarova et al [3] with the dehydration of n-butanol on H-ZSM-5 and amorphous aluminosilicate, and by Moravek and Kraus [4] with the ethanol dehydration on alumina.…”

Section: Introductionmentioning

confidence: 48%

In-situ characterisation of the surface intermediates for the ethanol dehydration reaction over γ-alumina under dynamic conditions

Golay

Doepper

Renken

1998

Applied Catalysis A: General

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The dynamic behavior of the ethanol adsorption on g-alumina were investigated at 180 and 2008C by the transient-response method coupled with FT±IR data of the catalyst surface. The existence of three adsorbates was demonstrated: a reacting species which is the precursor for the formation of the gas-phase ethene; an inhibiting species responsible for the low steadystate reaction rate; and a spectator species accumulating on the catalyst surface. Their infrared spectra indicate an ethoxidelike structure for the three adsorbates. Their C±H stretching bands can be depicted by four Lorentzians whose parameters indicate different surface environments. The surface concentration of the reacting species was determined on the basis of the transient ethene response. A value of 0.77AE0.07 mol/kg cat was found at 1808C. The surface concentration of the spectator species was determined by ex-situ thermogravimetric experiments. A value of 0.13AE0.01 mol/kg cat was found at 1808C. The most likely structure of this species corresponded to an ethanol molecule coordinated in a bidentate manner on Al 3 cations, with stabilisation of the alcoholic-hydroxyl group via lateral hydrogen bonding with an adjacent surface hydroxyl. # 1998 Elsevier Science B.V. All rights reserved.

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“…3 Comparison of the widespread prokaryotic fatty acid boxidation pathway and 1-butanol biosynthesis pathway in Clostridium acetobutylicum. Enzymes of E. coli and C. acetobutylicum are indicated by their gene names: atoB acetyl-CoA C-acetyltransferase; fadA (fadI) acetyl-CoA C-acyltransferase; fadB (fadJ) 3-hydroxyacyl-CoA dehydrogenase/ enoyl-CoA hydratase; fade (ydiO) acyl-CoA dehydrogenase; thlA, thlB thiolase (acetyl-CoA acetyltransferase); hbd 3-hydroxybutyryl-CoA dehydrogenase; crt crotonase (3-hydroxybutyryl-CoA dehydratase); bcd butyryl-CoA dehydrogenase (adapted from Gulevich et al 2011) modified aluminum oxides (Shen et al 1990;Macho et al 2001;Makarova et al 1990Makarova et al , 1994Berteau et al 1985;Berteau and Delmon 1989;Zhang et al 2010;Zotov et al 2010). The reaction conditions and the choice of the catalyst have an effect on the product distribution.…”

Section: Catalytic Upgrading N-butanolsupporting

confidence: 42%

Butanol production from lignocellulosics

et al. 2012

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Clostridium spp. produce n-butanol in the acetone/butanol/ethanol process. For sustainable industrial scale butanol production, a number of obstacles need to be addressed including choice of feedstock, the low product yield, toxicity to production strain, multiple-end products and downstream processing of alcohol mixtures. This review describes the use of lignocellulosic feedstocks, bioprocess and metabolic engineering, downstream processing and catalytic refining of n-butanol.

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Dehydration of n-Butanol on Zeolite H-ZSM-5 and Amorphous Aluminosilicate: Detailed Mechanistic Study and the Effect of Pore Confinement

Cited by 84 publications

References 0 publications

Reaction path analysis for 1-butanol dehydration in H-ZSM-5 zeolite: Ab initio and microkinetic modeling

Reaction path analysis for 1-butanol dehydration in H-ZSM-5 zeolite: Ab initio and microkinetic modeling

In-situ characterisation of the surface intermediates for the ethanol dehydration reaction over γ-alumina under dynamic conditions

Butanol production from lignocellulosics

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