Dehydrocoupling of ammonia and silanes catalyzed by dimethyltitanocene

Homogeneous Catalytic Hydrosilylation of Pyridines

“…[1±11] The reaction of Me 3 SiH with pyridine catalyzed by heterogeneous platinum-group catalysts was reported many years ago. [12] We now report the first examples of the hydrosilylation of pyridines with homogeneous, titanocene-based catalysts, and the first example of homogeneously catalyzed hydrosilylation of an aromatic substrate.…”

Synthesis ofβ-Mannosides via Prearranged Glycosides

“…Dendrimers provide the ultimate standard of a well-defined branched macromolecule, while hyperbranched polymers are less perfect elaborations of such three-dimensional structures. [2,3] The combination of controlled branching with block copolymerization provides additional opportunities to devise new molecular architectures. For instance, dendrimers have often been used as cores for the preparation of star polymers with a well-defined number of arms.…”

“…1998, 37, No. 22 variants [2] are most often only applicable to reactive glycosyl donors and acceptors or to special cases [3] efficient alternatives have been developed in recent years that allow for the selective preparation of 1,2-cis-configurated glycosides. The latter are accessible from 2-ulosyl bromides as glycosyl donors by diastereoselective reduction of the carbonyl group.…”

Organosilicon(IV) and organotin(IV) complexes as biocides and nematicides: synthetic, spectroscopic and biological studies of N∩N donor sulfonamide imine and its chelates

“…The contents were refluxed over a ratio head for [16][17][18] h and the white precipitate of sodium chloride obtained was removed under suction. The excess of the solvent was then removed over the ratio head and the compounds were dried under reduced pressure for 3-4 h. These were purified by repeated washing with a (1 : 1) mixture of dry methanol and cyclohexane.…”