2009
DOI: 10.1021/je900212d
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Densities and Viscosities of (1-Propanol + 1,2-Dichloroethane), (1-Propanol + Benzaldehyde), (Benzaldehyde + 1,2-Dichloroethane), and (1-Propanol + 1,2-Dichloroethane + Benzaldehyde) Mixtures from T = 288.15 K to 313.15 K

Abstract: Densities and viscosities of binary and ternary solvent systems which are composed of 1-propanol, 1,2-dichloroethane, and benzaldehyde have been measured in the temperature range (288.15 to 313.15) K and the over entire composition range and under atmospheric pressure. From experimental data, values of viscosity deviations, Δη, have been determined. The calculated binary data have been fitted to the Redlich−Kister equation to determine the appropriate coefficients. Also, the experimental results are used to de… Show more

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Cited by 27 publications
(9 citation statements)
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“…The temperature-dependent density changes of the solvent were corrected using equations and data from the International Critical Tables. [38][39][40][41] The complex solution was transferred into a coaxial 5 mm NMR tube containing a 1 mm capillary with the deuterated diamagnetic solvent and a small amount of tert-butanol as references. The residual 1 H NMR resonance of the tert-butanol methyl group was used for determining the susceptibility in solution.…”
Section: Single Crystal X-ray Data Collection and Structure Solutionmentioning
confidence: 99%
“…The temperature-dependent density changes of the solvent were corrected using equations and data from the International Critical Tables. [38][39][40][41] The complex solution was transferred into a coaxial 5 mm NMR tube containing a 1 mm capillary with the deuterated diamagnetic solvent and a small amount of tert-butanol as references. The residual 1 H NMR resonance of the tert-butanol methyl group was used for determining the susceptibility in solution.…”
Section: Single Crystal X-ray Data Collection and Structure Solutionmentioning
confidence: 99%
“…Table 1 contains provenance and purity of the chemicals used in this work. Purity of the solvents was ascertained by GLC and also by comparing their densities and viscosities at the experimental temperatures with the literature data [20][21][22][23][24][25][26][27][28][29][30][31], whenever available, as shown in Table S1 of the Supporting information.…”
Section: Chemicalsmentioning
confidence: 99%
“…Data processing and curve fitting were made by minitab version 15 and Sigma plot version 9-01. The details of the methods and techniques of the measurements have been described earlier [14][15][16].…”
Section: Apparatus and Proceduresmentioning
confidence: 99%
“…In this work, to continue and extend our previous studies [15,16] of interactions in liquid mixtures, we focus on the viscosity and volumetric measurements of the binary and ternary mixtures of cyclohexanone, 1,4-dioxane and isooctane at T = 288.15 K to 313.15 K and over the whole composition range for the liquid region and at ambient pressure. Cyclohexanone is useful in organic synthesis and used as precursor to Nylon 6.6 [17].…”
Section: Introductionmentioning
confidence: 98%