The calculation of the ionization probability and of the ionization coefficients of the holes of the spin split-off valence band in Ga1-
x
Al
x
Sb has been made for various compositions 0<x<0.08. This range allows us to obtain the situations in which the ratio of spin orbit splitting Δ to the energy gap E
g decreases from 1.05 to 0.89. It is shown that if the alloy disorder is neglected, the hole ionization coefficient k
p exhibits a continuous variation with Δ/E
g (or x); if not, k
p is strongly increased and shows a maximum for x=0.02 in the composition range in which Δ≥E
g (Δ/E
g=1.006). The comparison with experimental results is presented and allows an estimation of the mean free path of the holes; the strong influence of this parameter on the k
p values is discussed.