Dependence of Property of Silver Nanoparticles within Dendrimer‐template on Molar Ratios of Ag⁺ to PAMAM Dendrimers

Abstract

G5.0-OH PAMAM dendrimers were used to prepare fluorescent silver clusters with weaker ultraviolet irradiation reduction method, in which the molar ratio of Ag ＋ to PAMAM dendrimers was the key factor to determine the geometry and properties of silver nanoparticles. The results showed that because of G5.0-OH PAMAM dendrimers as strong encapsulatores, when the molar ratios of Ag ＋ to PAMAM dendrimers was smaller than 5, the obtained Ag n clusters (n＜5) had line structures and "molecular-like" properties, which were highly fluorescent and quite stable in aqueous solution. Whereas when the molar ratios were between 5 and 8, the obtained Ag n clusters were 2D structures and their fluorescence was weaker. When the molar ratio was larger than 8, the structure of silver nanoparticles was 3D and no fluorescence was observed from the obtained silver nanoparticles.

Synthesis and Characterization of Colloidal Fluorescent Silver Nanoclusters

“…The synthetic approaches to obtain Ag NCs previously reported follow two major synthetic routes . The stabilization of the Ag NCs can be made using polymers or dendrimers as ligand and/or scaffold, using DNA/oligonucleotides, or proteins for stabilization. Methods using an inorganic scaffold such as zeolites , have also been reported.…”