To
better understand the mechanisms of pulsed laser-assisted synthesis
of metal nitride, a numerical model was proposed to simulate the process
of laser nitriding of aluminum. The model incorporated various multiphysical
processes in the laser nitriding process, including heating, melting
and vaporization of aluminum, formation of plasma plume, shielding
of laser energy, ionization of nitrogen gas, and the transport of
nitrogen in the chemically active state N* (N atoms and N+ ions) inside the aluminum. The simulated results are in good agreement
with the existing experimental results in terms of laser intensity,
laser impulse, N+ lifetime in plume, and nitrogen diffusion
depth in aluminum. The model can well simulate the laser shielding
process by plume and the nitriding process of aluminum. Characteristics
of the plume expansion, plasma formation, nitrogen ionization, and
diffusion were investigated systematically by the developed model.
Investigations on the effects of key operating conditions show that
the impact of laser wavelength is negligible, while the full-width
at half-maximum (FWHM), nitrogen gas pressure, and laser intensity
have a significant impact on the laser nitriding process of aluminum.
The larger FWHM and larger laser intensity yield a layer with a higher
N* concentration and greater thickness. The higher nitrogen gas pressure
leads to an increase in N* concentration at the same position.