Deposition of Metals and Metal Oxides by Means of Metal Enolates

Abstract

Introduction Deposition Techniques Metal Deposition Metal Oxide Deposition

Crystal structure of (μ-1,4-dicarboxybutane-1,4-dicarboxylato)bis[bis(triphenylphosphane)silver(I)] dichloromethane trisolvate

“…Silver precursors [e.g. silver(I) carboxylates and silver(I) -diketonates] exhibit a wide range of applications, for instance the formation of thin, metallic layers by means of CVD (Chemical Vapour Deposition) or CCVD (Combustion Chemical Vapour Deposition) (Struppert et al, 2010;Jakob et al, 2006;Schmidt et al, 2005;Lang & Buschbeck, 2009;Lang, 2011;Lang & Dietrich, 2013;Chi & Lu, 2001), spin coating (Jakob et al, 2010) or inkjet printing (Jahn et al, 2010a,b;Gä bler et al, 2016). The respective silver layers show closed and homogeneous silver films and therefore possess a good conductivity.…”

Crystal structure of an unknown tetrahydrofuran solvate of tetrakis(μ3-cyanato-κ3N:N:N)tetrakis[(triphenylphosphane-κP)silver(I)]

“…A large number of studies about silver precursors, for instance silver(I) carboxylates, silver(I) dithiocarbamates or silver(I) -diketonates have been reported, due to their suitability in manifold application methods such as CCVD (combustion chemical vapour deposition) or CVD (chemical vapour deposition) processes (Struppert et al, 2010;Schmidt et al, 2005;Haase et al, 2005a,b;Lang & Buschbeck, 2009;Lang, 2011;Lang & Dietrich, 2013;Jakob et al, 2006;Chi et al, 1996;Chi & Lu, 2001), inkjet printing (Jahn et al, 2010), joining processes (Oestreicher et al, 2013), their use as single-source precursors for Ag 2 S formation (Mothes et al, 2015a,b), catalysis (Steffan et al, 2009) and self-assembly of silver nanoparticles (Bokhonov et al, 2014).…”

Synthesis, Characterization, and Electrochemistry of Diferrocenyl β-Diketones, -Diketonates, and Pyrazoles

“…Main-group element and transition metal β-diketonates, including Lewis-base adducts thereof, belong to one of the most investigated metal-organic complexes [ 1 , 2 , 3 , 4 , 5 , 6 , 7 ]. One reason is that they can be prepared by straightforward synthetic methodologies [ 8 , 9 , 10 ], and that many of them are commercially available.…”

“…One reason is that they can be prepared by straightforward synthetic methodologies [ 8 , 9 , 10 ], and that many of them are commercially available. Hence, they attained great interest in, for example, the deposition of metal or metal oxide thin layers by applying diverse deposition techniques, including CVD (=chemical vapor deposition) [ 1 , 11 , 12 , 13 , 14 ], ALD (=atomic layer deposition) [ 15 , 16 , 17 , 18 , 19 ], and spin-coating [ 20 , 21 , 22 ]. In addition, they received great interest in the synthesis of (hetero)multimetallic complexes [ 23 , 24 , 25 , 26 , 27 , 28 , 29 ] as catalysts in organic synthesis [ 30 , 31 , 32 ] and as anticancer drugs (especially copper and rhodium β-diketonates) [ 33 , 34 , 35 ].…”