Recent trend of the X-ray magnetic circular dichroism (XMCD) spectroscopy-based technique and the related scientific topics at SPring-8 are reviewed. At the third-generation synchrotron radiation facility, the key developments in the XMCD technique include i) significant improvements in the accuracy and sensitivity of XMCD measurements with a quick helicity switching of circularly polarized X-rays, ii) introduction of extreme conditions (strong pulsed magnetic field and high pressures), and iii) new experimental setup using the high-brilliance X-ray source (microfocusing, reflection geometry, and high-pressure cells). These achievements have effectively extended the capability of the XMCD technique, a unique magnetic probe with an element-specificity, providing fundamental scientific insights in spintronics and magnetic recording devices, magnetic nanoparticles, and magnetism under high-magnetic field and high pressures.KEYWORDS: X-ray magnetic circular dichroism, element specific magnetic hysteresis, synchrotron radiation X-rays
Historical ReviewElement-specific magnetic measurements are widely recognized as a powerful experimental technique for the study of magnetic materials and have previously been exploited mainly by Mössbauer spectroscopy. For the last 30 years, an energy-tunable and polarized X-ray source at synchrotron radiation facilities has given rather expansive possibilities of element-specific magnetic measurements using X-ray spectroscopy. Indeed, X-ray magnetic circular dichroism (XMCD) spectroscopy 1,2) has become one of the leading techniques for element-specific magnetic measurement using a resonant effect in the core-shell absorption with circularly polarized X-ray photons.The XMCD effect was first observed at the Fe K edge in the hard-X-ray region in 1987 by Schütz et al.3) In their experiment, an XMCD spectrum of pure iron was obtained by reversing the direction of magnetic fields applied to a sample, and the circularly polarized X-rays were provided by the off-orbital radiation from a bending magnet (off-plane method).3) The recorded XMCD signal was quite small, of the order of ÁI=I $ 5 Â 10 À3 . Subsequently, XMCD spectra at the L 2;3 edges of rare-earth elements [4][5][6] and at the L 2;3 edges of 5d metals in some alloys with 3d transition metals were also reported. 7) XMCD measurements over a wide energy range that is similar to the extended X-ray absorption fine structure (EXAFS), called magnetic EXAFS, in Fe and Gd 3 Fe 5 O 12 showed a capability of analyses of local magnetic structures using dichroic effects. 8,9) In the soft-X-ray region, the first XMCD spectrum at the Ni L 2;3 edges in a Ni single crystal was reported by Chen et al. in 1990. 10) The circularly polarized soft X-rays were obtained by the off-plain method, similar to the previous XMCD measurement at the Fe K edge.3) The intensity of the observed XMCD signal was about 8% with respect to the resonant absorption, the so called white line, and was much larger than that recorded at the K edge. The strong XMCD value at the...