We report the first observation of Bragg scattering from atomic ions confined in an electromagnetic trap. The results reveal long-range order and give evidence for bulk behavior in a strongly coupled collection of laser-cooled Be+ ions in a Penning trap. Long-range order emerges in approximately spherical clouds with as few as 5 X 104 ions (cloud radius ro = 37a where a = -Wigner-Seitz radius). Bulk behavior is evident with 2.7 X 10s trapped ions (ro = 65a), with Bragg scattering patterns characteristic of a body-centered cubic lattice. PACS numbers: 32.80.Pj, 52.25.Wz Systems of crystallized charged particles have gained wide interest, with implications for the pure Coulomb systems of one-component plasmas [1], trapped atomic ions [1 -3], ion storage rings [4], and dense astrophysical matter [5], and for the shielded Coulomb systems of colloidal suspensions [6] and dusty plasmas [7]. For example, Paul rf traps have been used to study crystallization and melting of small "Coulomb clusters" [8]. In both the rf and Penning traps, cold ions form shell structures when the dimensions