Large quantity of explosive is manufactured worldwide for use in various types of ammunition, arms, and mines, and used in armed conflicts. During manufacturing and usage of the explosive equipment, some of the explosive residues are released into the environment in the form of contaminated effluents, unburnt explosives fumes and vapours. Limited but uncontrolled continuous release of trace vapours also takes place when explosive-laden landmines are deployed in the field. One of the major technological challenges in post-war scenario worldwide is the detection of landmines using these trace vapour signatures and neutralising them safely. Different types of explosives are utilised as the main charge in antipersonnel and antitank landmines. In this paper, an effort has been made to review the techniques so far available based on explosive vapour detection especially to detect the landmines. A comprehensive compilation of relevant information on the techniques is presented, and their maturity levels, shortcomings, and difficulties faced are highlighted.