Along with the progress of electric network scale, power load and transmission lines are also growing rapidly in China. In addition, the transmission state detection is getting more and more attention. The paper explored the electric field under the HV (high voltage) line of transmission and researched the inverse operation principle of electric field. To solve the multiple parameter solutions in electric field inversion, the paper proposed two smart algorithms. Firstly, the fitness function of voltage value is extracted, therefore inversion algorithm global optimization function of the electric field is proposed. Secondly, an example of HV transmission line verified the effectiveness of the inverse optimization algorithm. Last, the case results indicate that the optimization methods are effective and accurate.