Step-bunching has attracted sustained attention due to
its remarkable
influence on the properties of SiC, which is a versatile functional
material in the power and optoelectronic fields. Here, step-bunching
morphology on the vicinal 4H-SiC surface is discovered to transform
among the morphologies with different step sizes and distribution
patterns in repeated annealing experiments. Meanwhile, a multiple-hill-valley
model, based on the experimental observations, is adopted to analyze
the surface energetics, from which the obtained morphologies are verified
to be metastable states that can be steadily maintained and thermally
accessible from one another. Moreover, for the purpose of elucidating
the surface morphology evolution at an atomic scale, molecular dynamics
simulations were performed. The results show that at high temperatures,
the fluctuation of the number of steps on the surface is extremely
active, while the final morphology depends on the cooling rate. Furthermore,
the change in step-bunching structure originates from larger steps
splitting and smaller ones merging, along with massive atomic migrations.
Finally, during the high-temperature process, the atomic trajectories
are basically localized along the peripheries of the (0001) facets.
These results provide insights into the mechanisms of step-bunching
formation and transformation, which are of referential significance
to the preparation and application of SiC for the next generation
of nanoelectronic technology.