The electrocaloric effect describes a reversible temperature change in dielectric materials submitted to an applied electric field. Adiabatic polarization raises their temperature, and adiabatic depolarization lowers it, analogous to temperature changes that occur when a gas is compressed or expanded. For refrigerator application, the reverse Brayton cycle is currently the most promising for practical implementation. The electrocaloric effect provides a large material efficiency. However, existing refrigerator prototypes lack from the absence of efficient heat switches for thermal linkage to the load and the heat sink. Cooling power densities of a few W/cm 2 and temperature spans in the order of 20 K (in regeneration systems) are achievable at a cycle time of 100 ms.Keywords: electrocaloric effect, thermodynamic cycles, coefficient of performance, refrigeration devices
IntroductionFor almost 150 years, refrigeration applications were solved by means of vapour compression. While the most efficient fluids for this approach are based on chlorofluorocarbons, hydrochlorofluorocarbons and hydrofluorocarbons, they come with the severe drawback of contributing to global warming and ozone depletion. Therefore, in 1987, the Montreal Protocol issued a ban on these chemicals providing regulations for phasing them out. Promising natural alternative substances are impractical due to their toxicity (ammonia) or-in particular-their flammability (propane) [1].Vapour compression refrigerators (VCRs) are operated as reverse Rankine cycles. They use a circulating liquid refrigerant as a medium. The refrigerant is: (i) adiabatically compressed, (ii) condensed at constant pressure undergoing a phase transition (thereby rejecting heat to the heat sink), (iii) adiabatically throttled in an expansion valve and (iv) evaporated at constant © 2017 The Author(s). Licensee InTech. This chapter is distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.pressure undergoing the reverse phase transition (thereby absorbing heat from the load). The amount of transferred heat is determined by the latent heat of the first-order phase transition. Similarly, in solid-state electrocaloric (EC) cooling, the adiabatic compression/expansion of the refrigerant is analogous to adiabatic polarization/depolarization, while the isobaric processes are replaced by isofield ones. Contrary to VCR, where the adiabatic expansion of the vapour is thermodynamically irreversible, the EC and the magnetocaloric (MC) effects are thermodynamically reversible processes that could reach the limit of the Carnot efficiency. This is another aspect making them promising for future application.Electric fields required for the EC refrigeration cycle can be supplied much easier and less expensively than the high magnetic fields required for the MC refrigeration [2]. Other advantages in compar...