The article considers the methodological aspects of the theoretical investigation of marine power plants with thermochemical fuel treatment. The results of the study of the complex influence of temperature, pressure, and the ratio of steam / base fuel on the thermochemical treatment efficiency are presented. The adequacy of the obtained regression dependences was confirmed by the physical modelling of thermochemical fuel treatment processes. For a gas turbine power complex with a thermochemical fuel treatment system, the characteristics of the power equipment were determined separately with further merging of the obtained results and a combination of material and energy flow models. Algorithms, which provide settings for the mathematical models of structural and functional blocks, the optimisation of thermochemical energy transformations, and verification of developed models according to the indicators of existing gas turbine engines, were created. The influence of mechanical energy consumption during the organisation of thermochemical processing of fuel on the efficiency of thermochemical recuperation is analysed.