Design and synthesis of covalent organic frameworks

Advanced functional polymer materials

“…COFs are a class of crystalline porous polymers assembled from organic building blocks by strong covalent bonds. [716][717][718][719][720][721][722] Different from traditional polymers, they allow the precise and atomically controllable integration of struts into long-ranged ordered networks. COFs feature extended porous structures with high surface area, large cavity, good thermal stability, and low density.…”

Construction of Triphenylamine‐based Two‐dimensional Covalent Organic Frameworks for High‐performance Capacitive Energy Storage and Exploration of Redox Units

“…As a new class of crystalline materials, the covalent organic frameworks (COFs), which are formed by covalent bond with carbon, hydrogen and other heteroatoms such as boron, nitrogen, oxygen and sulfur, have attracted great attention from many researchers. [1][2][3][4] Due to their unique properties, such as high porosity, low mass density, high surface area and excellent chemical stability, COFs have been used in the fields of photocatalysis, gas storage and separation, sensors, drug delivery and especially energy storage. [5][6][7][8][9][10] In 2013, Dichtel group first used 2D DAAQ-TFP COFs for pseudocapacitors, which were synthesized by condensing 2,6-diaminoanthraquinone and 1,3,5-triformylphloroglucinol.…”