2007
DOI: 10.1016/j.apcata.2006.10.052
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Design of nanostructured multifunctional Pd-based catalysts from layered double hydroxides precursors

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Cited by 39 publications
(27 citation statements)
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“…This preparation methodology has been widely used for the preparation of transition metal (NPs) supported catalysts, Ni, Cu and Pd being the most common monometallic reported systems. [58][59][60][61][62][63][64] Additionally, by introducing two different reducible cations in the LDH structure (e.g. Ni-Cu; [65][66][67] Ni-Co, [68][69][70] Pd-Cu, 71,72 among others), the subsequent thermal activation/ reduction can lead to the formation of bimetallic catalysts, whose catalytic and stability properties are generally better than those of the respective monometallic systems.…”
Section: Metal-supported Catalystsmentioning
confidence: 99%
“…This preparation methodology has been widely used for the preparation of transition metal (NPs) supported catalysts, Ni, Cu and Pd being the most common monometallic reported systems. [58][59][60][61][62][63][64] Additionally, by introducing two different reducible cations in the LDH structure (e.g. Ni-Cu; [65][66][67] Ni-Co, [68][69][70] Pd-Cu, 71,72 among others), the subsequent thermal activation/ reduction can lead to the formation of bimetallic catalysts, whose catalytic and stability properties are generally better than those of the respective monometallic systems.…”
Section: Metal-supported Catalystsmentioning
confidence: 99%
“…In comparison with the reaction scheme of MIBK synthesis (figure 1), there are more possibilities for selectivity loss in the synthesis of MPPAL, in particular, the self-condensation of propanal to oligomers. Before performing the full one-pot process in the liquid phase, the authors have studied the aldol condensation to 2-methyl-3-phenyl-propen-2-al alone (methylcinnamaldehyde, MCAL) with the aim to determine the best reaction conditions and the most efficient base catalyst for condensation [29]. Higher activity was found with Mg(Al)O as compared to MgO.…”
Section: Synthesis Of 2-methyl-3-phenyl-propanal (Mppal)mentioning
confidence: 98%
“…The one-pot synthesis of MPPAL from propanal and benzaldehyde (BAL) was reported on Pd supported on various basic solids, including Mg(Al)O [28,29]. The simplified reaction network is shown in figure 2.…”
Section: Synthesis Of 2-methyl-3-phenyl-propanal (Mppal)mentioning
confidence: 99%
“…Excess positive charge can make up for anions which are involved in the interslabs [215,216]. On account of the capacity for anions intercalation and exchange, LDH materials play a role in catalysis [217], magnetics [218,219], precursors to oxides [220], anion exchangers [221,222], and electrodes for rechargeable alkaline battery [223][224][225]. The representative cathode materials for alkaline battery include nickel hydroxide.…”
Section: Micro/nanostructured Al-based Materials For Nickel-metal Hydmentioning
confidence: 99%