Desorption of 1-butanol from polymeric resin: experimental studies and mathematical modeling

Abstract

Modeling of desorption kinetics and dynamic desorption process of 1-butanol from a polymeric resin.

Separation of Cytidine 5′-Monophosphate and Guanosine 5′-Monophosphate Based on the Hyper-Cross-Linked Resin XDA-1 with pH Gradient Elution

“…The surface diffusion model was obtained by employing some assumptions as follows: (i) surface diffusion is the main way of intraparticle diffusion; (ii) the resin particles are spherical; (iii) external mass transfer is neglected due to efficient mixing; and (iv) temperature is constant in the adsorption system …”

“…Fixed-bed adsorption is applied extensively to the separation of target compounds based on the adsorption method . Modeling is a significant tool to design and optimize the separation process of fixed-bed . Therefore, a lot of researchers studied the modeling of the separation process.…”

Comparing column dynamics in the liquid and vapor phase adsorption of biobutanol on an activated carbon monolith

“…Many alternatives have therefore been investigated and reviewed in literature (Abdehagh et al 2014;Ibrahim et al 2018;Kushwaha et al 2019) of which adsorption is one of the most promising (Qureshi et al 2005). The adsorptive recovery of biobutanol can be performed directly from the liquid fermentation broth (Abdehagh et al 2017;Cousin-Saint-Remi et al 2012;Faisal et al 2016;Faisal et al 2014;Gao et al 2017;Gao et al 2016;Groot and Luyben 1986;Jiao et al 2015;Lee et al 2016;Lin et al 2013;Lin et al 2012;Liu 2015;Maddox 1982;Nielsen and Prather 2009;Nielsen et al 1988;Oudshoorn et al 2009;Raganati et al 2018;Saravanan et al 2010;Staggs and Nielsen 2015;Wu et al 2015;Xue et al 2016;Yang et al 1994) or from gasses produced during gas or vacuum stripping of the fermentation broth (Abdehagh et al 2017;Bhattacharyya et al 2017;Cao et al 2015;Van der Perre et al 2017). Of the different adsorbents screened in literature for biobutanol recovery hydrophobic materials such as MFI zeolites (Abdehagh et al 2014;Cousin-Saint-Remi et al 2012;Maddox 1982;Milestone and Bibby 1983;Milestone and Bibby 1981), ZIF-8 (Cousin-Saint-Remi et al 2012;Cousin-Saint-Remi et al 2011;Gao et al 2017) and activated carbon materials (Abdehagh et al 2013...…”

3D-Printed ZIF-8 Monoliths for Biobutanol Recovery

“…However, the downstream processing for biobutanol is associated with a large energetic (24 MJ/kg butanol) and economic cost. , As an alternative to the traditional recovery via steam-stripping distillation, many techniques such as liquid–liquid extraction, membrane extraction, pervaporation gas stripping and adsorption have been investigated and extensive reviews are available in the literature. − One of the most promising alternatives for distillation is adsorption, which can lead to a significant decrease in energy consumption (8 MJ/kg butanol) . The recovery of biobutanol from the fermentation mixture via adsorption can be performed directly from the liquid fermentation broth − or from the gases produced during fermentation. ,− Among the different adsorbents evaluated for the recovery of biobutanol, ZIF-8 is one of the materials with the highest capacity and selectivity. ,, …”