Destruktive Komplexierung des dimeren Diorganylzinn(IV)-hydroxids [Me2Sn(A)(μ-OH)]2 (HA = Benzol-1,2-disulfonsäureimid): Bildung und Strukturen der Einkernkomplexe [Me2Sn(A)2(OPPh3)2] und [Me2Sn(phen)2]2⊕ · 2 A⊖ · MeCN

Wirth, Andreas; Moers, Oliver; Blaschette, Armand; Jones, Peter G.

doi:10.1002/(sici)1521-3749(200002)626:2<529::aid-zaac529>3.0.co;2-v

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Hypervalent Compounds of Organic Germanium, Tin and Lead Derivatives

Baukov

Tandura

2009

Patai's Chemistry of Functional Groups

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Introduction and Outline Self‐Associates Pentacoordinate Anionic Compounds Pentacoordinate Intermolecular Neutral Compounds Pentacoordinate Intramolecular Neutral Germanium Compounds Pentacoordinate Intramolecular Neutral Tin and Lead Compounds Pentacoordinate Cationic Compounds Hexacoordinate Anionic Compounds Hexacoordinate Neutral Compounds Hexacoordinate Cationic Tin Compounds Acknowledgments

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Hypervalent Compounds of Organic Germanium, Tin and Lead Derivatives

Baukov

Tandura

2009

Patai's Chemistry of Functional Groups

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Partially Fluorinated Rare Earth Metal Complexes

Neculai

Nikiforov

et al. 2003

Eur J Inorg Chem

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The reaction of LScBr2 (1), LYI2 (3), LHoI2 (4), or LErI2 (5) [L = N,N′′‐(1,3‐dimethyl‐1,3‐propanediylidene)bis(N′,N′‐diethyl‐1,2‐ethanediamine)] with Me3SnF was investigated. Treatment of 1 with Me3SnF results in the formation of (Me3BrSn‐μ‐F)2LSc (2) while compounds 3−5 give [LSnMe2][Me3SnI2] (6) as the only product that could be isolated and characterized. Metathesis reactions of 1 with AgSO3CF3 led to LSc(SO3CF3)2 (7). Compounds 1, 2, 6 and 7 were characterized by single‐crystal X‐ray structural analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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