We discuss and evaluate the expected performance of a tunable
multi-wavelength integrated-path differential absorption lidar
operating in the long-wave infrared between 7.5 and 11 µm, for
standoff measurement of chemical agents. Interference issues with
natural gas compounds throughout the entire 7.5–11 µm band are first
discussed. Then, the study focuses on four interest species, three
warfare agents, and a simulant. A performance model is derived and
exploited to assess the expectable measurement precision of the lidar
for these four species in the integrated-path mode within a 2 min
alert time and seventeen emitted wavelengths. Measurement precisions
better than the targeted sensitivity levels look reachable at the
kilometer range with laser power below 100 mW. Performance
optimization strategies are discussed, either by adjusting the pulse
energy/pulse repetition rate for a given laser power and lidar range
or by reducing the wavelength sequence in an optimal way. Finally the
system’s receiving operating characteristic curves are derived to
describe the expected detection performance in terms of probability of
false alarm rate and probability of detection.