The present research work explores the room temperature gas sensing ability of hybrid nanocomposites of metal sulphide nanoparticles with polypyrrole (PPy) matrix. Sonochemically synthesized both silver sulphide (Ag 2 S) and cadmium sulphide (CdS) nanoparticles were mixed in varying ratios with PPy matrix by in-situ oxidative polymerization route. The resulting PPy/(Ag 2 S:CdS) hybrid nanocomposites were analyzed by characterizing them using FTIR and UV-Visible spectroscopy, XRD, SEM, fourprobe conductivity method and gas sensing ability by two-probe gas sensing setup. The current-voltage (I-V) characteristics of the PPy hybrid nanocomposites revealed their semiconducting nature with an electrical conductivity in the range of 10 −4 to 10 −3 S/cm. As compared to pure PPy, their hybrid PPy/ (Ag 2 S:CdS) nanocomposites showed an enhancement in sensitivity towards ammonia gas detection. The results clearly indicated a synergistic effect between the Ag 2 S:CdS nanoparticles and the PPy matrix.