Determination of a N-methylcarbamate pesticide in environmental samples based on the application of photodecomposition and peroxyoxalate chemiluminescent detection

Soto‐Chinchilla, Jorge J.; Garcı́a-Campaña, Ana M.; Gámiz‐Gracia, Laura; Cuadros-Rodrı́guez, Luis; Vidal, José Luis Martı́nez

doi:10.1016/j.aca.2004.05.084

Cited by 27 publications

(18 citation statements)

References 14 publications

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“…The detection limits obtained were about 10 ng mL -1 , which, according to the authors, are comparable to that reported for other methods. 91 The peroxyoxalate system has also been used for the determination of phenol and 4-methylphenol in urine samples using HPLC post-column derivatization. After chromatographic separation, the phenols were transformed with dansyl chloride into fluorescent derivatives, which were subsequently detected by PO-CL acting as activators in the system.…”

Section: Analytical Applications Of Peroxyoxalate Chemiluminescencementioning

confidence: 99%

The chemiluminescent peroxyoxalate system: state of the art almost 50 years from its discovery

Francisco¹,

Ciscato²,

Augusto³

et al. 2012

Arkivoc

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Almost fifty years after the discovery of the peroxyoxalate reaction by E. A. Chandross in the early nineteen sixties, this review article intends to give a general overview on mechanistic aspects of this system and to describe the principles of its analytical application. After a short general introduction on the principles of chemiluminescence and the history of peroxyoxalate discovery, mechanistic aspects of high-energy intermediate formation, its structure and its reaction with an activator in the peroxyoxalate system are discussed. Finally, analytical applications of peroxyoxalate chemiluminescence are exemplified using representative recent examples, including oxalic acid detection in biological samples.

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Section: Analytical Applications Of Peroxyoxalate Chemiluminescencementioning

confidence: 99%

The chemiluminescent peroxyoxalate system: state of the art almost 50 years from its discovery

Francisco¹,

Ciscato²,

Augusto³

et al. 2012

Arkivoc

View full text Add to dashboard Cite

show abstract

“…The optimisation of the experimental variables affecting the CL intensity involved the use of different experimental designs and has been previously reported [12,13]. As a summary, the final optimum values for all the variables affecting in the FIA system are shown in Table 1.…”

Section: Chemical and Fia Variablesmentioning

confidence: 99%

“…Stock standard solutions of 100 mg l −1 of carbaryl (purity 99.9%, Dr. Ehrenstorfer GmbH), carbofuran, aldicarb and promecarb (purity 99.5%, Sigma-Aldrich) were prepared by dissolving 25 mg of each product in 25 ml of acetone, making up to 250 ml with water. The solutions were stored in the dark at 4 • C, and they are stable for at least 2 months [13]. Working solutions were freshly prepared by dilution of the stock solutions with water.…”

Section: Reagentsmentioning

confidence: 99%

“…Two Gilson Minipulse-3 peristaltic pumps, two Rheodyne 5020 manual injection valves (Rheodyne, L.P.), and Omnifit tubing and connections were used for constructing the FIA manifold, described elsewhere [10,12,13]. A water-bath (Selecta Mod.…”

Section: Apparatusmentioning

confidence: 99%

“…The advantages of the factorial analysis in the screening and optimisation of variables involved in the CL-FIA system have been previously reported [11]. In this sense, the proposed system has been optimised by means of a formal strategy based on the use of experimental designs [12], and applied to the quantitative analysis of carbaryl in water and cucumbers [13].…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

A new strategy for the chemiluminescent screening analysis of total N-methylcarbamate content in water

Soto‐Chinchilla

Gámiz‐Gracia

Garcı́a-Campaña

et al. 2005

Analytica Chimica Acta

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A review of recent developments based on chemiluminescence detection systems for pesticides analysis

Yahyai

Lawati

2020

Luminescence

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Chemiluminescence is one of the most coveted methods for sensitive determination of pesticides in food and environmental samples. To date, many methods have been developed for qualitative and quantitative analysis of pesticides, ranging from traditional to advanced methods. This study outlines the progress in the conventional and advanced analytical methods, coupled to a chemiluminescence detection system, that are employed for the determination of pesticides in food and environmental samples. Different analytical methods including chromatographic methods, flow‐based systems, and paper‐based systems are reviewed in this paper. As well, new advances in the application of nanomaterials, aptamer, and molecularly imprinted polymers are highlighted. We also address the challenges and difficulties associated with these methods. Finally, we highlight the future direction in this active field of research.

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Determination of a N-methylcarbamate pesticide in environmental samples based on the application of photodecomposition and peroxyoxalate chemiluminescent detection

Cited by 27 publications

References 14 publications

The chemiluminescent peroxyoxalate system: state of the art almost 50 years from its discovery

The chemiluminescent peroxyoxalate system: state of the art almost 50 years from its discovery

A new strategy for the chemiluminescent screening analysis of total N-methylcarbamate content in water

A review of recent developments based on chemiluminescence detection systems for pesticides analysis

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