2011
DOI: 10.1016/j.aca.2011.03.047
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Determination of antioxidant additives in foodstuffs by direct measurement of gold nanoparticle formation using resonance light scattering detection

Abstract: The capability of antioxidant compounds to reduce gold(III) to gold nanoparticles (AuNPs) has been kinetically studied in the presence of cetyltrimethylammonium bromide using stopped-flow mixing technique and resonance light scattering as detection system. This study has given rise to a simple and rapid method for the determination of several synthetic and natural antioxidant used as additives in foodstuff samples. The formation of AuNPs was monitored by measuring the initial reaction-rate of the system in abo… Show more

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Cited by 50 publications
(9 citation statements)
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“…In an attempt at antioxidant-surfactant combination by making use of light scattering rather than absorbance measurements, the capability of antioxidant compounds to enable Au(III)-AuNPs reduction was kinetically studied (in the presence of CTAB) with the stopped-flow mixing technique and a resonance light scattering (RLS) detection system, where the initial reaction rate for the formation of AuNPs was measured (22). When the initial rate of the system (as RLS signal per unit time) in the presence and absence of antioxidant was recorded against antioxidant concentration, a linear calibration curve was empirically obtained with relatively low limit of detection (LOD) values around 10 nmol L -1 for some food antioxidants.…”
Section: Nanoparticle-based Methods Of Total Antioxidant Capacity Meamentioning
confidence: 99%
“…In an attempt at antioxidant-surfactant combination by making use of light scattering rather than absorbance measurements, the capability of antioxidant compounds to enable Au(III)-AuNPs reduction was kinetically studied (in the presence of CTAB) with the stopped-flow mixing technique and a resonance light scattering (RLS) detection system, where the initial reaction rate for the formation of AuNPs was measured (22). When the initial rate of the system (as RLS signal per unit time) in the presence and absence of antioxidant was recorded against antioxidant concentration, a linear calibration curve was empirically obtained with relatively low limit of detection (LOD) values around 10 nmol L -1 for some food antioxidants.…”
Section: Nanoparticle-based Methods Of Total Antioxidant Capacity Meamentioning
confidence: 99%
“…Because Au nanoparticles (AuNPs) have many sensing applications [22][23][24], they have been used to evaluate antioxidant activity in foods, plants and beverages [5,18,[25][26][27][28][29][30][31][32][33][34]. Antioxidants present in plants and fruits can act as reductants and are able to reduce Au 3+ ions into gold nanoparticles (AuNPs).…”
Section: Introductionmentioning
confidence: 99%
“…Herein, we in-situ synthesized gold nanoparticles on filter paper. Though there is a similar approach to doing this, the reported works either quantified a total reducing power of a sample like tea and juice (dissolving a variety of antioxidants [20,21]) or using an enzyme to specify an analyte (i.e., glucose oxidase [22]).…”
Section: Introductionmentioning
confidence: 99%