Determination of Chlorpyrifos Pesticide Residue in Bell Peppers Grown in Dalat (Vietnam) by GC-MS/MS Using QuEChERS Extraction

Nguyen, Van-Trong; Tran, Long-Ho; Van, Thanh Khue; Le, Dinh-Vu

doi:10.1134/s106193482205015x

Cited by 5 publications

(3 citation statements)

References 18 publications

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“…Currently, multiple quantitative approaches including HPLC, 4 GC-MS/MS, 5 surface-enhanced Raman spectroscopy, 6 fluorescence, 7 magnetic relaxation switching biosensors, 8 enzyme-linked immunosorbent assay 9 and electrochemistry 10 have been developed for CPF detection. Among them, electrochemical biosensing techniques utilizing the inhibitory effect of CPF on acetylcholinesterase (AChE) activity have emerged as an important tool for trace CPF residual detection.…”

Section: Introductionmentioning

confidence: 99%

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS₂@N-CDs for chlorpyrifos detection

Chen,

Ji,

Wang

et al. 2024

RSC Adv.

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Section: Introductionmentioning

confidence: 99%

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS₂@N-CDs for chlorpyrifos detection

Chen,

Ji,

Wang

et al. 2024

RSC Adv.

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“…To overcome these effects, suitable preprocessing methods such as solid-phase extraction (SPE) and liquid–liquid extraction (LLE) [ 15 ] and QuEChERS for positive matrix effects [ 16 ] have been previously employed. Multiple studies have analyzed pesticide residues in sweet pepper by using QuEChERS along with gas chromatography triple quadrupole mass spectrometry (GC–MS/MS) and liquid chromatography (LC) MS/MS [ 17 , 18 , 19 ]. Nevertheless, unlike the analysis using MS/MS, very few studies have investigated the analysis of pesticide residues in sweet pepper using quadrupole time-of-flight mass spectrometry (QTOF-MS).…”

Section: Introductionmentioning

confidence: 99%

Ultra-High-Performance Liquid Chromatography Quadrupole Time-of-Flight Mass Spectrometry for Simultaneous Pesticide Analysis and Method Validation in Sweet Pepper

Bang¹,

Kim²,

Kim³

et al. 2023

Molecules

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Pesticides effectively reduce the population of various pests that harm crops and increase productivity, but leave residues that adversely affect health and the environment. Here, a simultaneous multicomponent analysis method based on ultra-high-performance liquid chromatography quadrupole time-of-flight mass spectrometry (UHPLC-QTOF-MS) pretreated by the QuEChERS method was developed to control the maximum residual levels. Among the 140 pesticides with high frequency of detection in agricultural products in Gyeongnam region in Korea for 5 years, 12 pesticides with high detection frequency in sweet pepper were selected. The analytical method is validated, linearities are r2 > 0.999, limit of detection (LOD) ranges from 1.4 to 3.2 µg/kg, and limit of quantification (LOQ) ranges from 4.1 to 9.7 µg/kg, and the recovery rate was 81.7–99.7%. In addition, it was confirmed that a meaningful value of these parameters can be achieved by determining the measurement uncertainty. The results proved that parameters such as recovery rate and relative standard deviation of the analysis method were within international standards. Using the developed method, better and safer sweet peppers will be provided to consumers, and effective pesticide residue management will be possible by expanding to other agricultural products.

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“…At present, chlorpyrifos residues are mainly detected by instrumental methods such as gas chromatography (GC) [ 4 , 5 ], gas chromatography-mass spectrometry (GC-MS) [ 6 , 7 , 8 , 9 ], high performance liquid chromatography (HPLC) [ 10 ], and liquid chromatography-mass spectrometry (LC-MS) [ 7 , 11 ]. Although these detection methods have the advantages of high accuracy and sensitivity, they require expensive instruments, professional technicians, tedious sample pretreatment processes, and large amounts of organic solvents, which limit their use for the rapid detection of chlorpyrifos residues in the field.…”

Section: Introductionmentioning

confidence: 99%

A Simple Aptamer SERS Sensor Based on Mesoporous Silica for the Detection of Chlorpyrifos

Dong

Shi

et al. 2022

Foods

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Chlorpyrifos is an organophosphorus insecticide, which can be used to control a variety of chewing and piercing mouthparts pests in agricultural production. It can destroy the normal nerve impulse conduction by inhibiting the activity of acetylcholinesterase or cholinesterase in the nerves, causing a series of poisoning symptoms. In order to achieve the quantitative analysis of chlorpyrifos residues in agricultural products, an aptamer-controlled signal molecule release method was developed in this study. The signal molecule 4-ATP of surface-enhanced Raman spectroscopy (SERS) was loaded into aminated mesoporous silica nanoparticles (MSNs-NH2) prepared by the one pot method, and then coated with an aptamer of chlorpyrifos through electrostatic interaction. The specific binding of the aptamer and chlorpyrifos led to the release of 4-ATP, and the amount of 4-ATP released was positively correlated with the amount of chlorpyrifos. Finally, the standard curve of chlorpyrifos quantitative detection based on SERS was established. Meanwhile, Ag-carrying mesoporous silica (Ag@MSNs) was prepared as the reinforcement substrate for SERS detection. The results showed that there was a good linear correlation between the Raman intensity and the concentration of chlorpyrifos at 25–250 ng/mL, and the limit of detection (LOD) was 19.87 ng/mL. The recoveries of chlorpyrifos in the apple and tomato samples were 90.08–102.2%, with RSD < 3.32%. This method has high sensitivity, specificity, reproducibility and stability, and can be used for the quantitative detection of chlorpyrifos in the environment and agricultural products.

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Determination of Chlorpyrifos Pesticide Residue in Bell Peppers Grown in Dalat (Vietnam) by GC-MS/MS Using QuEChERS Extraction

Cited by 5 publications

References 18 publications

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS₂@N-CDs for chlorpyrifos detection

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS₂@N-CDs for chlorpyrifos detection

Ultra-High-Performance Liquid Chromatography Quadrupole Time-of-Flight Mass Spectrometry for Simultaneous Pesticide Analysis and Method Validation in Sweet Pepper

A Simple Aptamer SERS Sensor Based on Mesoporous Silica for the Detection of Chlorpyrifos

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Determination of Chlorpyrifos Pesticide Residue in Bell Peppers Grown in Dalat (Vietnam) by GC-MS/MS Using QuEChERS Extraction

Cited by 5 publications

References 18 publications

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS2@N-CDs for chlorpyrifos detection

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS2@N-CDs for chlorpyrifos detection

Ultra-High-Performance Liquid Chromatography Quadrupole Time-of-Flight Mass Spectrometry for Simultaneous Pesticide Analysis and Method Validation in Sweet Pepper

A Simple Aptamer SERS Sensor Based on Mesoporous Silica for the Detection of Chlorpyrifos

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A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS₂@N-CDs for chlorpyrifos detection

A new plant-esterase inhibition based electrochemical sensor with signal amplification by MoS₂@N-CDs for chlorpyrifos detection