“…While the in situ analysis of materials during thermal annealing is well consolidated in the PD and XRR fields (although often limited to the exploration of only phase transitions and interface evolution, respectively), the number of in situ material HRXRD characterizations is much lower, although HRXRD gives access to specific information for epitaxial layers (lattice parameters, film thickness, composition, strain state, relaxation degree, dislocation density etc.). However, since the pioneering papers of , Zaumseil et al (1987) and Fabbri et al (1989), the number of HRXRD works exploiting thermal annealing and performed either using synchrotron sources (Lowe et al, 1991;Clarke et al, 1991;Lee & Baik, 1999;Stephenson et al, 2003;Skuza et al, 2007;Meduň a et al, 2007;Adell et al, 2007) or laboratory sources (e.g. Bai et al, 2004;Adell et al, 2005;Guinebretiere et al, 2007) has increased progressively.…”