1978
DOI: 10.1149/1.2131672
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Determination of Electron Affinity of In2 O 3 from Its Heterojunction Photovoltaic Properties

Abstract: In20~-Si, In203-Ge, Ir~203-GaAs, and I,n203-InP heterojunction solar cells have been fabricated and their photovoltaic properties have been investigated. All devices show rectifying and photovoltaic effects. The experimental results can be explained by a simple heterojunction energy band diagram. In order to match the experimentally observed polarities of the open-circuit voltage and short-circuit current of these heterojunction solar cells, the electron affinity of In203 materials is determined to be 4.45 eV.… Show more

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Cited by 36 publications
(4 citation statements)
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“…The vacuum levels in Fig. 1 are drawn with an electron affinity for In203 of 4.4 eV (34,35), a normal potential of the saturated calomel electrode of 0.25V (36), and a Fermi level of the normal hydrogen electrode referred to vacuum of 4.5 eV (37). Lowering of pH leads to an increase of the flatband potential (Fig.…”
Section: Semiconductor and Bilayermentioning
confidence: 99%
“…The vacuum levels in Fig. 1 are drawn with an electron affinity for In203 of 4.4 eV (34,35), a normal potential of the saturated calomel electrode of 0.25V (36), and a Fermi level of the normal hydrogen electrode referred to vacuum of 4.5 eV (37). Lowering of pH leads to an increase of the flatband potential (Fig.…”
Section: Semiconductor and Bilayermentioning
confidence: 99%
“…The typical bandgap data of Te and Ge is referred to determine their respective relative positions between conduction band minimum ( E C ) and valence band maximum ( E V ). [ 36,37 ] According to the above information, the energy band structure diagrams of p‐type Te and n‐type Ge are concluded, where E F of Te and Ge are close to their E V and E C , respectively. Figure 3f depicts the band energy level diagram of the heterojunction.…”
Section: Resultsmentioning
confidence: 96%
“…On the contrary, the binding energy of both Sn3d 3/2 and Sn3d 5/2 of In 2 O 3 /SnO 2 composite hetero-nanofibers moves to lower binding energy direction compared with Sn3d 3/2 (493.43 eV) and Sn3d 5/2 (485.03 eV) of pure SnO 2 nanofibers. This phenomenon, due to electron transfer, will occur from In 2 O 3 to SnO 2 until the energy-band diagram of the n-n heterojunction of In 2 O 3 /SnO 2 comes to equilibrium [ 14 , 34 , 35 ]. This phenomenon can also be explained by the strong interaction between In 2 O 3 and SnO 2 , which will lead to the decreased surface activity of SnO 2 and the increased surface activity of In 2 O 3 [ 36 ].…”
Section: Resultsmentioning
confidence: 99%