Determination of Natural Pesticides in Fresh Fruits Using Liquid Chromatography/Mass Spectrometry

Ruiz, Irene; Morales, Ascensión; Barba, A.; Oliva, J.

doi:10.5740/jaoacint.10-407

Cited by 5 publications

(3 citation statements)

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“…Several approaches to determine pesticide residues in citrus fruit − and processed citrus products, such as fruit soft drinks, , juices, , and essential oils, , have been developed. The most notable is the QuEChERS method and its different versions, , as well as the ethyl acetate method .…”

Section: Introductionmentioning

confidence: 99%

Matrix Effects and Interferences of Different Citrus Fruit Coextractives in Pesticide Residue Analysis Using Ultrahigh-Performance Liquid Chromatography–High-Resolution Mass Spectrometry

Besil

Cesio

Heinzen

et al. 2017

J. Agric. Food Chem.

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The matrix effects of ethyl acetate extracts from seven different citrus fruits on the determination of 80 pesticide residues using liquid chromatography coupled to high-resolution time-of-flight mass spectrometry (UHPLC-(ESI)-HR-TOF) at 4 GHz resolution mode were studied. Only 20% of the evaluated pesticides showed noticeable matrix effects (ME) due to coelution with natural products between t = 3 and 11 min. Principal component analysis (PCA) of the detected coextractives grouped the mandarins and the orange varieties, but separated lemon, oranges, and mandarins from each other. Matrix effects were different among species but similar between varieties, forcing the determination of pesticide residues through matrix-matched calibration curves with the same fruit. Twenty-three natural products (synephrine, naringin, poncirin, glycosides of hesperitin, limonin, nomilin, and a few fatty acids, among others) were identified in the analyzed extracts. Twelve of the identified compounds coeluted with 28 of the pesticides under study, causing different matrix effects.

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Section: Introductionmentioning

confidence: 99%

Matrix Effects and Interferences of Different Citrus Fruit Coextractives in Pesticide Residue Analysis Using Ultrahigh-Performance Liquid Chromatography–High-Resolution Mass Spectrometry

Besil

Cesio

Heinzen

et al. 2017

J. Agric. Food Chem.

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“…The method was linear within the investigated concentration range, displaying a calibration curve correlation factor of 0.99. The CVs obtained were below 20%, and recoveries were in the 70-110% range [35]. This paper describes a method for the sensitive and selective determination of two macrocyclic lactones (abamectin and spinosad) and azadirachtin in apple purée, concentrated lemon juice, tomato purée and canned peas.…”

Section: Ultimately We Have To Go For Natural Biopesticidesmentioning

confidence: 99%

An Urgent Need for Sustainable Agricultural Practices: A Review of Natural, Organic Ayurvedic and Homa Farming over Chemical Farming

Kumar¹,

Sharma²,

Meenakshi³

et al. 2018

AJRCS

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Agriculture lies at the heart of Indian civilization. The goal of sustainable agriculture is to integrate all factors into a production system that is appropriate for the environment, people, and local economic conditions. Another issue of great concern was the sustainability of soil productivity as land began to be intensively tilled to produce higher yields under multiple and intensive cropping systems. Water logging and secondary salinization have been the banes associated with excess and irrational irrigation. Groundwater table declined sharply as more and deeper bore wells were drilled. Recharging of groundwater has also been reduced due to severe deforestation. Indiscriminate use of chemical pesticides to control various insect pests and diseases over the years has destroyed many naturally occurring effective biological control agents. Sustainable organic farming practices needs proper eco-friendly pest and disease management practices in addition to balanced nutritional supplement to improve the quality and quantity of the agricultural outputs. Homemade bio-pesticides are prepared by household members using local resources without having any

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“…It was found that ascorbic acid stabilized labile pesticides and showed valid performance data. Ruiz et al (2012) developed an analytical procedure for the determination of some natural pesticides (piperonyl butoxide, nicotine, rotenone, spinosad and abamectin Bla) in fruit matrices.…”

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confidence: 99%

Analytical Methods for Pesticide Residues

Liang¹,

Bilon²,

Hay³

2013

Water Environment Research

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A review of literature published in 2012 on analytical methods for pesticides is presented here that includes papers on extraction methods and analytical methods such as chromatographic and spectrometric techniques, spectrophotometric techniques, fluorescence and chemiluminescence techniques, biochemical assays and immunoassays, electrochemical methods, and review articles on analytical methods. Because many of the research studies in the cited publications utilized more than one analytical method, the different sections should not be considered mutually exclusive.

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Determination of Natural Pesticides in Fresh Fruits Using Liquid Chromatography/Mass Spectrometry

Cited by 5 publications

References 0 publications

Matrix Effects and Interferences of Different Citrus Fruit Coextractives in Pesticide Residue Analysis Using Ultrahigh-Performance Liquid Chromatography–High-Resolution Mass Spectrometry

Matrix Effects and Interferences of Different Citrus Fruit Coextractives in Pesticide Residue Analysis Using Ultrahigh-Performance Liquid Chromatography–High-Resolution Mass Spectrometry

An Urgent Need for Sustainable Agricultural Practices: A Review of Natural, Organic Ayurvedic and Homa Farming over Chemical Farming

Analytical Methods for Pesticide Residues

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