Determination of Tetraalkyllead by High Performance Liquid Chromatography with ICP Detection

Ibrahim, Mona; Gilbert, T. W.; Caruso, Joseph A.

doi:10.1093/chromsci/22.3.111

Cited by 32 publications

(5 citation statements)

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“…An HPLC system can be very easily coupled to an ICP by connecting the column outlet to the ICP nebuliser using a short piece of tubing (Ibrahim et al, 1984) The tubing should be as short as possible to maintain good resolution. The problem with this system is that the ICP nebuliser is very inefficient and instead of 100% transfer of analyte into the plasma this is usually only between 1% and 20%.…”

Section: Hplc Coupled With Icp Spectrometric Detectionmentioning

confidence: 99%

“…The direct injection nebuliser was probably the most useful of the interfaces developed giving the best reported detection limits; however, the system was not easy to use due to its fragility. Environmental applications of HPLC-ICPAES include the determination of lead species with limits of detection of 42 ppb Pb (Ibrahim et al, 1984) and the determination of chromium species with limits of detection in the 10 ng region (Nakata et al, 1985). However, since it has become more widely available, ICP-MS has largely taken over from ICPAES due to its higher sensitivity (see Section 4.4.4).…”

Section: Hplc Coupled With Icp Spectrometric Detectionmentioning

confidence: 99%

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Hybrid Methods of Speciation

Greenway¹

2002

Chemical Speciation in the Environment

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Section: Hplc Coupled With Icp Spectrometric Detectionmentioning

confidence: 99%

Section: Hplc Coupled With Icp Spectrometric Detectionmentioning

confidence: 99%

Hybrid Methods of Speciation

Greenway¹

2002

Chemical Speciation in the Environment

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“…For the analysis of chemical speciation, different methods have been employed by various researchers. Among these methods are the voltammetric method (Bard and Faulkner, 1980;Bond, 1980), the liquid-liquid extraction method (Francis et al, 2001;Meera et al, 2001), the ion-exchange and adsorption columns/resins method (Morel et al, 2008;Sweileh et al, 1987), the gas chromatography method (Dietz et al, 2000;Rodil et al, 2002), the liquid chromatography method (Ibrahim et al, 1984;Weber et al, 2002), the capillary electrophoresis (CE) method (Rocha et al, 2000;Yin et al, 2002), and the Inductively Coupled Plasma Mass Spectrometry (ICP-MS) method (Butcher, 2007;Medel et al, 2003). The ICP-MS method in particular can be a good tool for sensitive speciation analyses of many environmentally important elements.…”

Section: Introductionmentioning

confidence: 99%

Chemical Species of Metallic Elements in the Aquatic Environment of anEx‐Mining Catchment

Ashraf¹,

Ahmad²,

Akib³

et al. 2014

Water Environment Research

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This study was conducted to investigate the chemical speciation of dissolved and particulate elements (lead, zinc, copper, chromium, arsenic, and tin) in the mining wastewater of a former tin mining catchment. The speciation patterns of dissolved elements were estimated by an adsorptive stripping voltammeter (ASV), while particulate elements were analyzed by using a newly developed sequential-extraction leaching procedure. The procedure has been operationally defined among five host fractions, namely exchangeable, carbonate, reducible, organic bound, and residual fractions. A total of six elements (lead, zinc, copper, chromium, arsenic, and tin) were analyzed in thirty samples at ten locations (P1-P10), with three samples taken from each of the ten locations, to get the average value from the former tin-mining catchment. The results showed that the heavy metal pollutions in locations P4 and P8 were more severe than in other sampling sites, especially tin and lead pollution. In the water samples from locations P4 and P8, both the total contents and the most dangerous non-residual fractions of tin and lead were extremely high. More than 90% of the total concentrations of arsenic and chromium existed in the residual fraction. Concentrations of copper and zinc mainly occurred in the residual fraction (more than 60%), while lead and tin presented mostly in the non-residual fractions in surface water. For all of the six dissolved elements, the less-labile species formed the predominant fraction in their speciation patterns. The speciation patterns of particulate elements showed that most of the concentrations of zinc, copper, chromium, and arsenic were found in the reducible fraction; whereas lead and tin were mainly associated with the organic fraction. Water Environ. Res., 86, 717 (2014).

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“…For analysis of chemical speciation, different methods have been employed by different researchers such as voltammetry (Bard and Faulkner, 1980;Bond, 1980), liquid -liquid extraction (Meera et al, 2001;Francis et al, 2001), ion exchange and adsorption columnsyresins (Morel et al, 2008;Sweileh et al, 1987), gas chromatography (Dietz et al, 2000;Rodil et al, 2002), liquid chromatography (Ibrahim et al, 1984;Weber et al, 2002), capillary electrophoresis (CE) (Rocha et al, 2000;Yin et al, 2002) as well as inductively coupled plasma mass spectrometry (ICP-MS) (Medel et al, 2003;Butcher, 2007). ICP-MS could be useful tool for sensitive speciation analyses of many environmentally important elements.…”

Section: Introductionmentioning

confidence: 99%

Speciation of heavy metals in the surface waters of a former tin mining catchment

Ashraf

Maah

Yusoff

et al. 2012

Chemical Speciation & Bioavailability

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This study was conducted to investigate the chemical speciation of dissolved and particulate elements (Pb, Zn, Cu, Cr, As and Sn) in the mining wastewater. Speciation patterns of dissolved elements were estimated by adsorptive stripping voltammeter while particulate elements were analysed using a newly developed sequential extraction leaching procedure. The procedure has been operationally defined among five host fractions, namely exchangeable, carbonate, reducible, organic bound and residual. A total of six elements (Pb, Zn, Cu, Cr, As and Sn) were analysed in 30 samples at 10 locations (P1 -P10) representing three subsequent samples at the same location to obtain the average value from ex-tin mining catchment. The results showed that the heavy metal pollution in P4 and P8 was more severe than in other sampling sites, especially Sn and Pb pollution. In the water samples at P4 and P8, both the total contents and the most dangerous non-residual fractions of Sn and Pb were extremely high. More than 90% of the total concentrations of As and Cr existed in the residual fraction. Cu and Zn mainly (more than 60%) occurred in the residual fraction. However, Pb and Sn were predominantly present in the non-residual fractions of the surface water. For all the six dissolved elements, the less labile species formed the predominant fraction in their speciation patterns. We conclude that the speciation patterns of particulate elements show that most of the Pb, Zn, Cu, Cr, As and Sn were found in the reducible fraction whereas Pb and Sn were mainly associated with the organic fraction.

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Determination of Tetraalkyllead by High Performance Liquid Chromatography with ICP Detection

Cited by 32 publications

References 0 publications

Hybrid Methods of Speciation

Hybrid Methods of Speciation

Chemical Species of Metallic Elements in the Aquatic Environment of anEx‐Mining Catchment

Speciation of heavy metals in the surface waters of a former tin mining catchment

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