ABSTRACT:The degree of contamination by heavy metals (arsenic, copper, lead, tin and zinc) in soil and transfer to plants has been studied. Specimens of plant species from five locations in an area of 10 x 10 m were sampled with their corresponding soils. Thirty six plant species including two shallow water aquatic plants were identified. Soil and plant specimens were analyzed by using inductively coupled plasma optical emission spectrometry. It was found that metal concentration in soil was highly variable while concentration of metals in plants directly depends on the concentration of metals it was rooted. Roots showed highest metal concentration followed by leaves, shoots and flowers. Bioconcentraion factor and translocation factor were calculated, representing Cyperus rotundus L. as a potential tin-hyperaccumulator plant, previously not reported in literature. Plant Species Imperata cylindrica, Lycopodium cernuum, Melastoma malabathricum, Mimosa pudica Linn, Nelumbo nucifera, Phragmites australis L., Pteris vittata L. and Salvinia molesta, were metal accumulator while Acacia podalyriaefolia G. Don, Bulb Vanisium, Dillenia reticulate King, Eugenia reinwardtiana, Evodia roxburghiania Hk. f. clarke, Gleichenia linearis, Grewia erythrocarpa Ridl., Manihot esculenta Crantz, Paspalum conjugatum Berguis, Passiflora suberosa, Saccharum officinarum, Stenochlaena palustris (Burm.) Bedd. and Vitis trifolia Linn. were tolerated plant species. All other studied plants were excluders. Identified plant species could be useful for revegetation and erosion control in metals contaminated ex-mining sites. Morphological changes such as reduction in size, change in color and deshaping have also been observed in plant species with high metal values.

This study describes the chemical speciation of Pb, Zn, Cu, Cr, As, and Sn in soil of former tin mining catchment. Total five sites were selected for sampling and subsequent subsamples were collected from each site in order to create a composite sample for analysis. Samples were analysed by the sequential extraction procedure using optical emission spectrometry (ICP OES). Small amounts of Cu, Cr, and As retrieved from the exchangeable phase, the ready available for biogeochemical cycles in the ecosystem. Low quantities of Cu and As could be taken up by plants in these kind of acidic soils. Zn not detected in the bioavailable forms while Pb is only present in negligible amounts in very few samples. The absence of mobile forms of Pb eliminates the toxic risk both in the trophic chain and its migration downwards the soil profile. The results also indicate that most of the metals have high abundance in residual fraction indicating lithogenic origin and low bioavailability of the metals in the studied soil. The average potential mobility for the metals giving the following order: Sn > Cu > Zn > Pb > Cr > As.

This study investigated the impacts of climate change on the Chalk aquifer in west Norfolk. A two-layer transient groundwater flow model of the aquifer system was calibrated and validated for the period 1980-1995 and provided the historic flow record for the climate change simulations. Two future scenarios were selected from the Hadley Centre's climate change experiments using HadCM2: (1) a medium-high (MH) emissions scenario; and (2) a medium-low (ML) emissions scenario of 'greenhouse' gases. Two future periods were considered: 2020-2035 and 2050-2065. Future recharge to the aquifer was estimated by adjusting the historic record of monthly precipitation and potential evapotranspiration by factors calculated from comparing control and future HadCM2-generated values. Impacts of climate change were evaluated by incorporating the monthly estimated recharge inputs within the flow model. The most noticeable and consistent result of the climate change impact simulations is the decrease in recharge expected in autumn for all scenarios (decreases ranging from 17 to 35%) as a consequence of the smaller amount of summer precipitation and increased autumn potential evapotranspiration. For the 2050MH scenario, these conditions lead to a 42% increase in autumn soil moisture deficit and a 26% reduction in recharge. Hence, west Norfolk can expect longer and drier summers that are predicted to have relatively little effect on summer groundwater levels (generally a 1 to 2% decrease) but will result in a decrease of up to 14% in autumn river baseflow volumes.

Three new series of biologically active amino substituted Schiff bases with general formula, R1N=CHR2. Here R1=2-amino-benzthiazole, 4-amino-salicylic acid and 4-aminophenol. R2 =4-chloro-benzaldehyde, 2-chloro-benzaldehyde, salicylaldehyde, vanillin and benzaldehyde were synthesized by the reaction of three different amino substituted compounds and substituted aldehydes in ethanol. Such compounds were characterized by different physico-chemical techniques like, melting point, elemental analysis, multinuclear nmr (1H, 13C). The free ligands and their metal complexes have been screened for their in vitro biological activities against bacteria, fungi and yeast. The metal complexes show more potent activities compared with Schiff base ligands.