Electrically generated spin–orbit torque (SOT)
has emerged
as a powerful pathway to control magnetization for spintronic applications
including memory, logic, and neurocomputing. However, the requirement
of external magnetic fields, together with the ultrahigh current density,
is the main obstacle for practical SOT devices. In this paper, we
report that the field-free SOT-driven magnetization switching can
be successfully realized by interfacial ion absorption in perpendicular
Ta/CoFeB/MgO multilayers. Besides, the tunable SOT efficiency exhibits
a strong dependence on interfacial Ti insertion thicknesses. Polarized
neutron reflection measurements demonstrate the existence of canted
magnetization with Ti inserted, which leads to deterministic magnetization
switching. In addition, interfacial characterization and first-principles
calculations reveal that B absorption by the Ti layer is the main
cause behind the enhanced interfacial transparency, which determines
the tunable SOT efficiency. Our findings highlight an attractive scheme
to a purely electric control spin configuration, enabling innovative
designs for SOT-based spintronics via interfacial engineering.