Development and Validation of the Successor to the Weisenberger–Schumpe Solubility Model of Gas in Aqueous Electrolytes: Solubilities of Ar, He, Xe, and O₃ in Electrolyte Solutions at 25 °C

Abstract

A new expression for the Weisenberger−Schumpe gas solubility model in electrolyte solutions is proposed. Novel and previously published experimental data are analyzed to develop a model that allows for more accurate K S (Sechenov constants) calculations than the state-of-the-art Weisenberger−Schumpe model and suggests that the effect of dissolving gas type on K S depends on the magnitude of this constant. The concentration dependences of the Henry's constants for Ar, He, Xe, and O 3 in NaCl, LiClO 4 , NaClO 4 , Mg(ClO 4 ) 2 , Na 2 SO 4 , CdSO 4 , K 2 HPO 4 , and Al 2 (SO 4 ) 3 salt solutions were investigated at 25 °C, and the corresponding K S of these systems were determined.

Ozone in Polar (Acetonitrile) and Nonpolar (Carbon Tetrachloride) Organic Liquids: Optical Absorption, Solubility, and Stability

“…The solubility of a substance is determined by its polarity and polarity of the solvent used. [9,10] Therefore, it is necessary that the polar and nonpolar liquids used in the process be resistant to oxidation and, in particular, to the action of ozone in a wide temperature range, including temperatures below 273.15 K. The ozone solubility and stability in a liquid are important parameters. In addition, it is desirable that the solvent be optically transparent in the range convenient for monitoring the kinetics of the solute and ozone consumption and product formation by absorption spectrophotometry.…”

“…To intensify the oxidation, it is necessary to create the optimum conditions ensuring the stability of the reaction medium and the sufficient concentrations of ozone and the substrate being oxidized in the reaction zone. The solubility of a substance is determined by its polarity and polarity of the solvent used [9,10] . Therefore, it is necessary that the polar and nonpolar liquids used in the process be resistant to oxidation and, in particular, to the action of ozone in a wide temperature range, including temperatures below 273.15 K. The ozone solubility and stability in a liquid are important parameters.…”