Development of a silicon carbide fibre with high tensile strength

Silicon-Based Polymer-Derived Ceramics: Synthesis Properties and Applications-A Review

“…20,40,78,[94][95][96][97][98][99][100][101][102][103][104][105][106][107][108][109] Several polymers derived from vinylsilanes, 98 disilylaryls, 110 allylsilanes and cyclocarbosilanes 111 can be used as precursors for SiC-based ceramics.…”

“…10. 29 Si MAS NMR of SiCO and SiBCO samples. péÉÅá~ä fëëìÉ Äó dìÉëí bÇáíçêëW lêÖ~åáÅ-íç-fåçêÖ~åáÅ`çåîÉêëáçå mêçÅÉëë Ñçê mçäóãÉê-aÉêáîÉÇ`Éê~ãáÅë polysiloxanes 230 in inert or reactive atmospheres.…”

Precipitation Processing to Synthesize Fine Polycarbosilane Particles for Precursors of Silicon Carbide Powders

“…In addition, lower processing temperatures than conventional sintering methods are one of industrial merit of polymer precursor routes. Since continuous SiC fibers derived from polycarbosilane PCS were developed in 1970's, 8 many kinds of polymers were developed for precursors with the consequence that SiC based fibers with excellent properties were used for industrial applications. 9,10 PCS has the advantages of stability in air and water, while many organometallic polymers are much sensitive to air and water.…”

Interaction in polysilazane/SiC powder systems

“…This was speculated on by Niihara32but no microstructural evidence was given. Equation (8) shows also that Vg is proportional to Vp' For reasons that will become clear in the next chapter (microstructure) it seems rational to choose a large precursor loading. In view of the density results after pyrolysis ( fig.…”