The effects of Sc and Zr on the shape, size, and number density of Al 6 (Mn,Fe) phase in Al5Mg0.7Mn alloys were investigated by this article. The results showed that Sc and Zr can form strengthening particles of Al 3 Sc and Al 3 (Sc,Zr), which have the effect of refining grains and modifying the morphology and distribution of Al 6 (Mn,Fe) phase. The OM, SEM, and TEM images indicate that with the formation of primary Al 3 Sc and Al 3 (Sc,Zr), the shape of Al 6 (Mn,Fe) became more regular, size of Al 6 (Mn,Fe) became smaller, and the number density of Al 6 (Mn,Fe) increased when compared with base alloy. Zr could motivate the precipitation of primary Al 3 (Sc,Zr) and Al5Mg0.7Mn0.2Sc0.2Zr had better refining effect than Al5Mg0.7Mn0.4Sc. The grain refinement and finely dispersed Al 6 (Mn,Fe) phase can improve the mechanical properties such as yield strength and ultimate tensile strength and the corrosion resistance by the results of intergranular corrosion (IGC) also improved.